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2006 | 109 | 4-5 | 583-589
Article title

XANES Study of La_{0.75-x}Gd_xCa_{0.25}MnO_{3-δ} Solid Solutions

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Languages of publication
EN
Abstracts
EN
A series of solid solutions La_{0. 75-x}Gd_xCa_{0.25}MnO_{3-δ} with 0.0≤x≤0.75 was prepared via carbonate precursor precipitation method. Final sintering was performed at 1250ºC in oxygen flow atmosphere. The samples obtained were characterized by scanning electron microscope, X-ray diffraction measurements. Oxygen stoichiometry was analyzed by iodometric titration method. X-ray absorption spectroscopic methods of Mn L-edge and Mn K-edge X-ray absorption near edge structure were used to study oxidation state of manganese in the solid solutions and elucidate features of their local crystal structure. Orthorhombic crystal structure characteristics of the solid solutions were refined by Rietveld method. An increase in oxygen deficiency and average manganese oxidation state were found to accompany Gd concentration increase in La_{0.75-x}Gd_xCa_{0.25}MnO_{3-δ}. These results are consistent with Mn L-edge X-ray absorption near edge structure spectra, where a gradual change of Mn oxidation state with Gd concentration increase was detected. Origins of oxygen deficiency La_{0.75- x}Gd_xCa_{0.25}MnO_{3-δ} are discussed in terms of structural disorder caused by Gd substitution for La.
Keywords
EN
Publisher

Year
Volume
109
Issue
4-5
Pages
583-589
Physical description
Dates
published
2006-04
received
2005-09-25
Contributors
author
  • Department of Chemistry, Kiev National Taras Shevchenko University, 60 Volodymyrska, Kiev, 01033 Ukraine
  • Department of Chemistry, National Taiwan University, Roosevelt Road, Section 4, Taipei 106, Taiwan, ROC
author
  • Department of Chemistry, Warsaw University, Żwirki i Wigury 101, Warsaw, Poland
author
  • Department of Chemistry, National Taiwan University, Roosevelt Road, Section 4, Taipei 106, Taiwan, ROC
author
  • National Synchrotron Radiation Research Centre, Hsinchu 300, Taiwan, ROC
author
  • National Synchrotron Radiation Research Centre, Hsinchu 300, Taiwan, ROC
References
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv109n422kz
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