PL EN


Preferences help
enabled [disable] Abstract
Number of results
2006 | 109 | 3 | 399-404
Article title

The Interaction of Water with Glycine: A Combined Inelastic Neutron Scattering and Raman Spectra Studies

Authors
Content
Title variants
Languages of publication
EN
Abstracts
EN
The vibrational dynamics of water around glycine was investigated by using Raman spectroscopy and inelastic neutron scattering. Experiments of deuterated glycine versus deuterium were performed as comparison. The study shows that for glycine, the exchange of proton-deuteron on the active NH_3^+ side was easy, whereas there was hardly exchange on the CH_2 side. Comparing different proportion of glycine vs. water molecules we obtained that the presence of water hardly changes the main features of glycine illustrating its hydrophobic character. The intralayer hydrogen bonds of glycine crystal are difficult to be replaced due to its stronger bond than water.
Keywords
Year
Volume
109
Issue
3
Pages
399-404
Physical description
Dates
published
2006-03
received
2005-05-20
References
  • 1. G.L. Perlovich, L.K. Hansen, A. Baur-Brandl, J. Therm. Anal. Calorimetry, 66, 699, 2001
  • 2. G. Albrecht, R.B. Corey, J. Am. Chem. Soc., 61, 1087, 19
  • 3. P.-G. Jonsson, A. Kvick, Acta Crystallogr. B, 28, 1827, 1972
  • 4. R.E. Marsh, Acta Crystallogr., 11, 654, 1958
  • 5. R. Ramaekers, J. Pajak, B. Lambie, G. Maes, J. Chem. Phys., 120, 4182, 2004
  • 6. J.C. Li, J. Chem. Phys., 105, 6733, 1996
  • 7. J.C. Li, M.J. Leslie, J. Phys. Chem., 101, 6304, 1997
  • 8. K. Furić, V. Mohacek, M. Bonifacić, I. Stefanić, J. Mol. Struct., 267, 39, 1992
  • 9. S. Suzuki, T. Shimanouchi, M. Tsuboi, Spectrochim. Acta A, 19, 1195, 1963
  • 10. S.F.A. Kettle, E. Lugwisha, J. Echet, N.K. McGuire, Spectrochim. Acta A, 45, 533, 1989
  • 11. K. Machida, A. Kagayama, Y. Saito, Y. Kuroda, T. Uno, Spectrochim. Acta A, 33, 569, 1977
  • 12. H.J. Himmler, H.H. Eysel, Spectrochim. Acta, 45, 1077, 1989
  • 13. R.S. Krishnan, K. Krishnan, Proc. Ind. Acad. Sci. A, 60, 11, 1964
  • 14. D.H. Williams, I. Fleming, Spectroscopic Methods in Organic Chemistry, McGraw-Hill, UK 1995
  • 15. J.C. Li, D.K. Ross, Nature, 365, 327, 1993
Document Type
Publication order reference
YADDA identifier
bwmeta1.element.bwnjournal-article-appv109n322kz
Identifiers
JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.