Photoinduced Nonlinear Effects in C_{60}-2-thioxo-1,3-di thiole and C_{60}-TTF Derivatives

• Authors: A. Migalska-Zalas , I. Fuks-Janczarek , S. Dabos-Seignon , B. Sahraoui , I. Kityk , E. Allard , D. Kreher , J. Cousseau , P. Hudhomme , A. Gorgue
• Languages of publication: EN

Abstracts

EN

Photoinduced effects in pure C_{60}:C_{60}-TTF and C_{60}-2-thioxo-1,3-dithiole cycloadducts are investigated using nonlinear optical techniques. We have studied photoinduced optical second harmonic generation, two-photon absorption, linear electro-optics, and quadratic electro-optic effect coefficient versus applied pressure (p) and temperature (T). We deduce the influence of the grafted substituents in pure C_{60} on the observed photoinduced effects. The obtained results illustrate clearly that the photoinduced nonlinear optics can be used as a tool to detect structural changes at low temperature in modified C_{60}. We have unambiguously demonstrated that, under the applied hydrostatic pressure up to 19 GPa and the temperature from 4.2 up to 150 K, the observed effects are essentially caused by the grafted TTF derivatives.

Keywords

EN

42.65.An

Discipline

• 42.65.An: Optical susceptibility, hyperpolarizability[see also 33.15.Kr Electric and magnetic moments (and derivatives), polarizability, and magnetic susceptibility]

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2003
• Volume: 103
• Issue: 2-3
• Pages: 283-292

Dates

published

2003-02/03

received

2002-09-05

Contributors

author

A. Migalska-Zalas

• University of Angers, POMA Laboratory, CNRS UMR, 6136, 2 bd Lavoisier, 49045 Angers, France
• Institute of Physics WSP, al. Armii Krajowej 13/15, 42-201 Częstochowa, Poland

author

I. Fuks-Janczarek

• University of Angers, POMA Laboratory, CNRS UMR, 6136, 2 bd Lavoisier, 49045 Angers, France
• Institute of Physics WSP, al. Armii Krajowej 13/15, 42-201 Częstochowa, Poland

author

S. Dabos-Seignon

• University of Angers, POMA Laboratory, CNRS UMR, 6136, 2 bd Lavoisier, 49045 Angers, France

author

B. Sahraoui

• University of Angers, POMA Laboratory, CNRS UMR, 6136, 2 bd Lavoisier, 49045 Angers, France

author

I. Kityk

• Institute of Physics WSP, al. Armii Krajowej 13/15, 42-201 Częstochowa, Poland

author

E. Allard

• Laboratoire d'Ingénierie Moléculaire et Matériaux Organiques, UMR CNRS 6501, Université d'Angers, 2 bd Lavoisier, 49045 Angers, France

author

D. Kreher

• Laboratoire d'Ingénierie Moléculaire et Matériaux Organiques, UMR CNRS 6501, Université d'Angers, 2 bd Lavoisier, 49045 Angers, France

author

J. Cousseau

• Laboratoire d'Ingénierie Moléculaire et Matériaux Organiques, UMR CNRS 6501, Université d'Angers, 2 bd Lavoisier, 49045 Angers, France

author

P. Hudhomme

• Laboratoire d'Ingénierie Moléculaire et Matériaux Organiques, UMR CNRS 6501, Université d'Angers, 2 bd Lavoisier, 49045 Angers, France

author

A. Gorgue

• Laboratoire d'Ingénierie Moléculaire et Matériaux Organiques, UMR CNRS 6501, Université d'Angers, 2 bd Lavoisier, 49045 Angers, France

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Identifiers

DOI

10.12693/APhysPolA.103.283