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La_{1-x}MnO_3 films grown by metal organic chemical vapor deposition technique on r-plane cut Al_2O_3 substrates were investigated. The change of the optical response over the La_{1-x}MnO_3/Al_2O_3 sample surface was investigated along with the temperature dependence of magnetization. The mostly pronounced difference in the spectra of dielectric function occurred in the region of the d-d transitions of Mn-ions. The changes in the optical spectra and magnetic properties were correlated to the structural features of thin film.