Pressure Broadening of J=1 ← 0 Rotational Line of Fluoroform Caused by Spherical Perturbers

• Authors: S. Gierszal , J. Galica , E. Miś-Kuźmińska , A. Liber
• Languages of publication: EN

Abstracts

EN

The foreign-gas broadening parameter was measured for CHF_3 molecule interacting with spherical (SF_6, CF_4, CH_4, CCl_4) perturbers and the pressure shift parameter of rotational transition J=1 ← 0 in the CHF_3 molecule was obtained. For the systems of trifluoromethane molecule and four spherical molecules as perturbers the collision cross-sections were determined. Experimental line width parameters are interpreted using Anderson-Tsao-Curnutte as well as Murphy-Boggs theories. Accounting for the dispersive and inductive interactions the cross-section was determined. The theoretical values are in qualitative agreement with the experimental results, but the absolute values of the measured cross-section were larger than these calculated.

Keywords

EN

33.20.Bx; 33.20.Sn

Discipline

• 33.20.Sn: Rotational analysis
• 33.20.Bx: Radio-frequency and microwave spectra

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2002
• Volume: 101
• Issue: 6
• Pages: 805-813

Dates

published

2002-06

received

2001-11-02

(unknown)

2002-02-25

Contributors

author

S. Gierszal

• Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznań, Poland

author

J. Galica

• Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznań, Poland

author

E. Miś-Kuźmińska

• Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznań, Poland

author

A. Liber

• Computer Science Department, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

References

• 1. C.O. Britt, J.E. Boggs, J. Chem. Phys., 45, 3877L, 1966
• 2. S. Murphy, J.E. Boggs, J. Chem. Phys., 47, 4152, 1967
• 3. W.A. Wensink, C. Noorman, H.A. Dijkerman, J. Phys. B, At. Mol. Phys., 12, 1687, 1979
• 4. B.T. Berendts, A. Dymanus, J. Chem. Phys., 48, 1361, 1968
• 5. D.S. Olson, C.O. Britt, V. Prakash, J. Boggs, J. Phys. B, At. Mol. Phys., 6, 206, 1973
• 6. S. Gierszal, J. Galica, E. Miś-Kuźmińska, J. Chem. Phys., 108, 8976, 1998
• 7. P.W. Anderson, Phys. Rev., 76, 647, 1949
• 8. C.J. Tsao, B. Curnutte, J. Quantum Spectrosc. Radiat. Transfer, 2, 42, 1962
• 9. J.S. Murphy, J.E. Boggs, J. Chem. Phys., 47, 691, 1967
• 10. Krishnaji, S.L. Srivastava, J. Chem. Phys., 41, 2266, 1964
• 11. S. Gierszal, J. Galica, E. Miś-Kuźmińska, Acta Phys. Pol. A, 79, 451, 1991
• 12. J. Galica, S. Gierszal, E. Miś-Kuźmińska, Phys. Scr., 53, 648, 1996
• 13. S. Gierszal, J. Galica, E. Miś-Kuźmińska, J. Chem. Phys., 108, 8976, 1998
• 14. S. Gierszal, J. Galica, E. Miś-Kuźmińska, Phys. Scr., 61, 581, 2000
• 15. H. Odashima, M. Kajita, Y. Matsuo, T. Minowa, J. Chem. Phys., 90, 4875, 1989
• 16. G. Birnbaum, Advance Chemical Physics, Vol. XII, Intermolecular Forces, Wiley, New York 1967
• 17. Handbook of Chemistry and Physics, D.R. Lide, 78th ed., CRC Press, New York 1997-1998
• 18. Program MINDO/3 POLAR PRECISE
• 19. A. Rosenberg, G. Birnbaum, J. Chem. Phys., 48, 1396, 1968
• 20. A. Rosenberg, G. Birnbaum, J. Chem. Phys., 52, 682, 1970
• 21. Y.J. Kime, D.C. Driscoll, P.A. Dowben, J. Chem. Soc. Faraday Trans. 2, 83, 403, 1987
• 22. S.M. Breitling, A.D. Jones, R.B. Boyd, J. Chem. Phys., 54, 3959, 1971
• 23. J.O. Hirschfelder, C.F. Curtis, R.B. Bird, Molecular Theory of Gases and Liquids, Wiley, New York 1967

Identifiers

DOI

10.12693/APhysPolA.101.805