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2018 | 133 | 2 | 244-249
Article title

Synthesis and Characterization of a Novel Aminoketooxime Ligand and Enzymatic Efficiencies of Its Metal Complexes

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EN
Abstracts
EN
A novel aminoketooxime ligand and its mononuclear Cu(II) and Mn(II) complexes were synthesized. The structures of the synthesized compounds were illuminated by elemental analysis, inductively coupled plasma optical emission spectrometry, the Fourier transform infrared, ¹H- and ¹³C-NMR, UV-Vis, magnetic susceptibility and conductivity measurements. According to the characterization studies ligand to metal ratio was found to be 2:1 with strong binding affinity of the ligand to the metal ions. In addition, complexes have been tested for their catecholase and phenoxazinone synthase-like activities. Kinetic studies were also carried out yielding V_{max}, k_{cat} and K_{M} values of both complexes for catecholase and phenoxazinone synthase-like activities. Both complexes efficiently catalyzed the reactions of the enzymes they mimicked.
Publisher

Year
Volume
133
Issue
2
Pages
244-249
Physical description
Dates
published
2018-02
Contributors
author
  • Faculty of Education, Mehmet Akif Ersoy University, Burdur, Turkey
author
  • Faculty of Science and Arts, Süleyman Demirel University, Isparta, Turkey
author
  • Faculty of Science and Arts, Süleyman Demirel University, Isparta, Turkey
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-app133z2p08kz
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