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Abstracts
SBA-15-SO₃H supported tungstophosphoric acid (TPA, H₃PW₁₂O₄₀) mesoporous materials were synthesized by impregnation of TPA into the hydrothermally synthesized SBA-15-SO₃H and the catalytic performances were compared for the esterification reaction. The physical and chemical properties of the catalysts were characterized by XRD, SEM/EDX, FT-IR and N₂ adsorption/desorption techniques. The characterization results show that TPA/SBA-15-SO₃H retained the typical mesoporous structure of SBA-15-SO₃H. The experimental results indicated that TPA/SBA-15-SO₃H is a more efficient catalyst than SBA-15-SO₃H for the esterification reaction. The higher activity of TPA/SBA-15-SO₃H compared with that of SBA-15-SO₃H was consistent with the material having the low pKa value, confirming that the esterification rate was mostly dependent on the acid strength of the additional functional groups of solid acid catalyst. Accordingly, the reason for the catalytic activity difference was simply explicated by the effect of TPA, having low pKa value, affecting the pore structure and the total acidity.
Discipline
- 61.43.Gt: Powders, porous materials
- 82.65.+r: Surface and interface chemistry; heterogeneous catalysis at surfaces(for temporal and spatial patterns in surface reactions, see 82.40.Np; see also 82.45.Jn Surface structure, reactivity and catalysis in electrochemistry; see also 68.43.-h Chemisorption/physisorption: adsorbates on surfaces)
Journal
Year
Volume
Issue
Pages
1041-1044
Physical description
Dates
published
2017-09
Contributors
author
- Uludag University, Chemistry Department, Bursa, Turkey
author
- Uludag University, Physics Department, Bursa, Turkey
author
- Eskişehir Osmangazi University, Chemical Engineering Department, Eskisehir, Turkey
author
- Anadolu University, Material Science and Engineering Department, Eskisehir, Turkey
author
- Anadolu University, Material Science and Engineering Department, Eskisehir, Turkey
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-app132z3-iip062kz