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2007 | 54 | 4 | 679-693

Article title

A biomimetic approach to some specifically functionalized cyclic terpenoids

Content

Title variants

Languages of publication

EN

Abstracts

EN
The paper relates on the current advancements in the synthesis of complex cyclic terpenoids by superacidic induced cyclization of open chain precursors. It is shown that functional groups disposal in the initial substrate strongly influences the reaction outcome. Possible variations of the investigated compound structures include particularly α-functionalization and α,ω-bifunctionalization. This approach allowed a selective initiation of cyclization sequence from an internal double bond or suspending the ring closure cascade to partially cyclized compounds. The reported synthetic schemes are attempts to mimic the biogenetical processes postulated in the living systems.

Keywords

Year

Volume

54

Issue

4

Pages

679-693

Physical description

Dates

published
2007
received
2007-08-23
revised
2007-11-23
accepted
2007-12-03
(unknown)
2007-12-12

Contributors

  • Institutul de Chimie al AŞM, Chişinău, Republica Moldova

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.bwnjournal-article-abpv54p679kz
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