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2007 | 54 | 4 | 679-693
Article title

A biomimetic approach to some specifically functionalized cyclic terpenoids

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EN
Abstracts
EN
The paper relates on the current advancements in the synthesis of complex cyclic terpenoids by superacidic induced cyclization of open chain precursors. It is shown that functional groups disposal in the initial substrate strongly influences the reaction outcome. Possible variations of the investigated compound structures include particularly α-functionalization and α,ω-bifunctionalization. This approach allowed a selective initiation of cyclization sequence from an internal double bond or suspending the ring closure cascade to partially cyclized compounds. The reported synthetic schemes are attempts to mimic the biogenetical processes postulated in the living systems.
Keywords
Publisher

Year
Volume
54
Issue
4
Pages
679-693
Physical description
Dates
published
2007
received
2007-08-23
revised
2007-11-23
accepted
2007-12-03
(unknown)
2007-12-12
Contributors
  • Institutul de Chimie al AŞM, Chişinău, Republica Moldova
References
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-abpv54p679kz
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