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2012 | 19 | 3 | 383-391

Article title

A Critical View on the Phenol Index as a Measure of Phenol Compounds Content in Waters. Application of a Biosensor

Content

Title variants

Languages of publication

EN

Abstracts

EN
Phenol index is considered as an important indicator of water purity and quality. Usually phenol index is determined by a spectrophotometric method the calibration being based on phenol standards. Unfortunately, the absorptivities of different phenols compounds differ from each other. This leads to significant uncertainty concerning content of phenols in water. It is shown that the same shortage of the phenol index appears also if it is determined using an amperometric biosensor based on tyrosinase. The sensitivity of the biosensor response to four phenol compounds: phenol, catechol, 3-cresol and 4-chlorophenol was examined, as well as possible interactions between phenols, according to 24 factorial experiment. It was proved that individual phenols affect phenol index independently from each other, ie no significant interaction between phenols was detected. However, sensitivity of the biosensor to different phenols is not the same. Relationship between phenol index and concentrations of phenols in water is discussed.
PL
Indeks fenolowy jest ważnym wskaźnikiem czystości i jakości wody. Oznacza się go zwykle metodami spektrofotometrycznymi z 4-aminoantypiryną, stosując fenol jako wzorzec. Ponieważ współczynniki absorpcji różnych związków fenolowych różnią się, wyznaczona wartość indeksu fenolowego obarczona jest znaczną niepewnością. Podobny efekt występuje, gdy indeks fenolowy oznaczany jest przy użyciu biosensora amperometrycznego opartego na tyrozynazie. W pracy wyznaczono czułości biosensora w stosunku do czterech związków fenolowych: fenolu, katecholu, 3-krezolu oraz 4-chlorofenolu oraz zbadano możliwe interakcje pomiędzy fenolami. Doświadczenia prowadzono według planów czynnikowych 24. Wykazano, że poszczególne fenole wpływają na indeks fenolowy niezależnie od siebie, tzn. nie stwierdzono istotnych interakcji pomiędzy fenolami. Jednak czułość biosensora jest różna w stosunku do różnych fenoli. Przedyskutowano zależność pomiędzy indeksem fenolowym a stężeniami fenoli w wodzie.

Publisher

Year

Volume

19

Issue

3

Pages

383-391

Physical description

Dates

published
1 - 1 - 2012
online
16 - 7 - 2012

Contributors

  • Department of Analytical Chemistry, Jagiellonian University, ul. R. Ingardena 3, 30-060 Kraków, Poland
  • Department of Analytical Chemistry, Jagiellonian University, ul. R. Ingardena 3, 30-060 Kraków, Poland
  • Department of Analytical Chemistry, Jagiellonian University, ul. R. Ingardena 3, 30-060 Kraków, Poland

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_v10216-011-0028-5
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