Full-text resources of PSJD and other databases are now available in the new Library of Science.
Visit https://bibliotekanauki.pl

PL EN


Preferences help
enabled [disable] Abstract
Number of results
2012 | 33 | 2 | 207-219

Article title

Distillation profiles in ternary heterogeneous mixtures with distillation boundaries: staged columns

Content

Title variants

Languages of publication

EN

Abstracts

EN
Distillation boundaries originate from saddle azeotropes, dividing the composition space into distillation regions. In heterogeneous mixtures distilled in packed columns, distillation regions overlap. The common area of distillation regions is parametrically sensitive, and it determines the possibilities of crossing (at a finite reflux) the distillation boundaries defined for a total reflux or reboil ratio. This work is an extended research of the paper (Królikowski et al., 2011) conducted to scrutinize whether the distillation regions overlapped in heteroazeotropic systems distilled in staged columns. Presented studies were performed by finding such composition points of the products, for which the rectifying profiles of staged columns were ended in different distillation regions. Calculations were executed for the heterogeneous mixture classified under Serafimov's topological class as 3.1-2: ethanol - benzene - water. Distillation regions for staged columns were found to overlap each other in the heterogeneous systems. As a result, their common part was parametrically sensitive.

Publisher

Year

Volume

33

Issue

2

Pages

207-219

Physical description

Dates

published
1 - 6 - 2012
online
5 - 7 - 2012

Contributors

  • Chemical Engineering Institute, Wrocław University of Technology, ul. C.K. Norwida 4/6, 50-373 Wrocław, Poland

References

  • Antoine C., 1888. Vapor pressures: new relationship between vapor pressure and temperature. Records of meetings of the Academy of Sciences, 107, 681-684, 778-780, 836-837 (in French).
  • Baur R., Krishna R., Taylor R., 2005. Influence of mass transfer in distillation: feasibility and design. AIChE J., 51, 854-866. DOI: 10.1002/aic.10328.[Crossref]
  • Bossen B.S., Bay Jargensen, S., Gani R., 1993. Simulation, design, and analysis of azeotropic distillation operations. Ind. Eng. Chem. Res., 32, 620-633. DOI: 10.1021/ie00016a008.[Crossref]
  • Brüggemann S., Marquardt W., 2011a. Conceptual design of distillation processes for mixtures with distillation boundaries. II. Optimization of recycle policies. AIChE J., 54, 1540-1556. DOI: 10.1002/aic.12377.[WoS][Crossref]
  • Brüggemann, S., Marquardt, W., 2011b. Conceptual design of distillation processes for mixtures with distillation boundaries: I. Computational assessment of split feasibility. AIChE J., 57, 1526-1539. DOI: 10.1002/aic.12378.[WoS][Crossref]
  • Castillo F.J.L., Towler G.P., 1998. Influence of multicomponent mass transfer on homogeneous azeotropic distillation. Chem. Eng. Sci., 53, 963-976. DOI: 10.1016/s0009-2509(97)00418-1.[Crossref]
  • Doherty M.F., Caldarola G.A., 1985. Design and synthesis of homogeneous azeotropic distillations. 3. The sequencing of columns for azeotropic and extractive distillations. Ind. Eng. Chem. Fundam., 24, 474-485. DOI: 10.1021/i100020a012.
  • Fidkowski Z.T., Doherty M.F., Malone M.F., 1993. Feasibility of separations for distillation of nonideal ternary mixtures. AIChE J., 39, 1303-1321. DOI: 10.1002/aic.690390806.[Crossref]
  • Gmehling J., Menke J., Krafczyk J., Fischer K., 2004. Azeotropic data. 2nd edition. 3 Vols. Wiley-VCH, Weinheim.
  • Gmehling J., Onken U., Arlt W., 1977. Vapor-liquid equilibrium data collection. DECHEMA Chem. Data Ser., Frankfurt.
  • Jobson M., Hildebrandt D., Glasser D., 1995. Attainable products for the vapour-liquid separation of homogeneous ternary mixtures. Chem. Eng. J. Biochem. Eng. J., 59, 51-70. DOI: 10.1016/0923-0467(95)03002-6.[Crossref]
  • Kiva V.N., Hilmen E.K., Skogestad S., 2003. Azeotropic phase equilibrium diagrams: A survey. Chem. Eng. Sci., 58, 1903-1953. DOI: 10.1016/s0009-2509(03)00018-6.[Crossref]
  • Królikowski A.R., Królikowski L.J., Wasylkiewicz S.K., 2007. Properties of distillation boundaries in ternary heterogeneous mixtures. XIX Polish Conference of Chemical and Process Engineering. Rzeszów, Poland, 3-7 September 2007, 87-90 (in Polish).
  • Królikowski A.R., Królikowski L.J., Wasylkiewicz S.K., 2011. Distillation profiles in ternary heterogeneous mixtures with distillation boundaries. Chem. Eng. Res. Des., 89, 879-893. DOI: 10.1016/j.cherd.2010.11.016.[Crossref]
  • Królikowski L.J., 1999. Selection of separation conditions of heteroazeotropes, In: SPR Reports, Report SPR 8/99. Institute of Chemical Engineering and Heating Equipment, Wrocław University of Technology, Poland, p. 22 (in Polish).
  • Królikowski L.J., 2001. Distillation boundaries created by the ternary azeotropes. Chem. Proc. Eng., 22, 807-812 (in Polish).
  • Królikowski L.J., 2002. Distillation regions for nonideal ternary mixtures. International Conference of Distillation and Absorption, Baden-Baden, Germany, 30 September-2 October 2002, Section 6-19.
  • Królikowski L.J., 2003. Determination of distillation regions for ternary azeotropic mixtures. IVth Symposium on Distillation, Absorption and Extraction. Szklarska Poręba, Poland, 6-8 October 2003, 34-40 (in Polish).
  • Królikowski L.J., 2006. Determination of distillation regions for non-ideal ternary mixtures. AIChE J., 52, 532-544. DOI: 10.1002/aic.10663.[Crossref]
  • Levy S.G., Van Dongen D.B., Doherty M.F., 1985. Design and synthesis of homogeneous azeotropic distillations. 2. Minimum reflux calculations for nonideal and azeotropic columns. Ind. Eng. Chem. Fundam., 24, 463-474. DOI: 10.1021/i100020a011.[Crossref]
  • Lucia A., Taylor R., 2006. The geometry of separation boundaries: I. Basic theory and numerical support. AIChE J., 52, 582-594. DOI: 10.1002/aic.10668.[Crossref]
  • Lucia A., Taylor R., 2007. The geometry of separation boundaries. II. Mathematical formalism. AIChE J., 53, 1779-1788. DOI: 10.1002/aic.11204.[WoS][Crossref]
  • Mortaheb H.R., Kosuge H., 2004. Simulation and optimization of heterogeneous azeotropic distillation process with a rate-based model. Chem. Eng. Process., 43, 317-326. DOI: 10.1016/s0255-2701(03)00131-4.[Crossref]
  • Petlyuk F.B., Platonov V.M., Slavinskii D.M., 1965. Thermodynamically optimal method for separating multicomponent mixtures. Int. Chem. Eng., 5, 555-561.
  • Renon H., Prausnitz J.M., 1968. Local compositions in thermodynamic excess functions for liquid mixtures. AIChE J., 14, 135-144. DOI: 10.1002/aic.690140124.[Crossref]
  • Renon H., Prausnitz J.M., 1969. Estimation of parameters for the NRTL equation for excess Gibbs energies of strongly nonideal liquid mixtures. Ind. Eng. Chem. Process Des. Dev., 8, 413-419. DOI: 10.1021/i260031a019.[Crossref]
  • Rév E., 1992. Crossing of valleys, ridges, and simple boundaries by distillation in homogeneous ternary mixtures. Ind. Eng. Chem. Res., 31, 893-901.[Crossref]
  • Safrit B.T., Westerberg A.W., 1997. Algorithm for generating the distillation regions for azeotropic multicomponent mixtures. Ind. Eng. Chem. Res., 36, 1827-1840. DOI: 10.1021/ie960344r.[Crossref]
  • Serafimov L.A., 1970. The azeotropic rule and the classification of multicomponent mixtures VII. Diagrams for ternary mixtures. J. Phys. Chem. (USSR), 44, 567-642.
  • Shampine L.F., Reichelt M.W., 1997. The MATLAB ODE suite. SIAM J. Sci. Comput., 18, 1-22. DOI: 10.1137/S1064827594276424.[Crossref]
  • Springer P.A.M., van der Molen S., Krishna R., 2002. The need for using rigorous rate-based models for simulations of ternary azeotropic distillation. Comput. Chem. Eng., 26, 1265-1279. DOI: 10.1016/s0098-1354(02)00039-x.[Crossref]
  • Taylor R., Baur R., Krishna R., 2004. Influence of mass transfer in distillation: residue curves and total reflux. AIChE J., 50, 3134-3148. DOI: 10.1002/aic.10278.[Crossref]
  • Teixeira J.C., Sena Jr. F.C., Silva A.M.V., Stragevitch L., Silva J.M.F., 2009. Moving boundary in non-equilibrium simple batch distillation in non-ideal systems. Chem. Eng. Proc.: Process Intensification, 48, 1574-1578. DOI: 10.1016/j.cep.2009.10.013.[Crossref]
  • Van Dongen D.B., Doherty M.F., 1984. On the dynamics of distillation processes-V: the topology of the boiling temperature surface and its relation to azeotropic distillation. Chem. Eng. Sci., 39, 883-892. DOI: 10.1016/0009-2509(84)85057-5.[Crossref]
  • Wahnschafft O.M., Koehler J.W., Blass E., Westerberg A.W., 1992. The product composition regions of single-feed azeotropic distillation columns. Ind. Eng. Chem. Res., 31, 2345-2362. DOI: 10.1021/ie00010a014.[Crossref]

Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_v10176-012-0018-x
JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.