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2012 | 33 | 1 | 7-18
Article title

Reaction kinetics of CO2 in aqueous methyldiethanolamine solutions using the stopped-flow technique

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EN
Abstracts
EN
The kinetics of the reaction between CO2 and methyldiethanolamine in aqueous solutions have been studied using the stopped-flow technique at 288, 293, 298 and 303 K. The amine concentration ranged from 250 to 875 mol·m-3. The overall reaction rate constant was found to increase with amine concentration and temperature. The acid base catalysis mechanism was applied to correlate the experimentally determined kinetic data. A good agreement between the second order rate constants for the CO2 reaction with MDEA computed from the stopped-flow data and the values reported in the literature was obtained.
Publisher

Year
Volume
33
Issue
1
Pages
7-18
Physical description
Dates
published
1 - 3 - 2012
online
6 - 3 - 2012
Contributors
  • Faculty of Process and Environmental Engineering, Technical University of Lodz, ul. Wólczańska 213, 90-924 Łódź, Poland
  • Faculty of Process and Environmental Engineering, Technical University of Lodz, ul. Wólczańska 213, 90-924 Łódź, Poland
  • Faculty of Process and Environmental Engineering, Technical University of Lodz, ul. Wólczańska 213, 90-924 Łódź, Poland
References
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_v10176-012-0001-6
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