Synthesis and characterization of Pt/CeOx systems for catalytic CO oxidation reaction

• Authors: R. Wróbel , S. łagonda , U. Narkiewicz , R. Pełech , S. Becker , L. Szymaszkiewicz
• Languages of publication: EN

Abstracts

EN

Four different ceria supported catalyst were prepared by impregnation method with Pt(NO3)2 solution. The two supports are commercially available (MaTeck) and the other two were prepared by precipitation and microwave assisted hydrothermal method (MAH) respectively. The phase composition and average crystallite size of the catalysts were characterised with XRD technique. Finally the catalytic activity in CO oxidation reaction were determined in plug flow reactor in temperature range 300-900 K with 1 K resolution. The catalysts obtained in both precipitation and MAH methods exhibit catalytic activity at room temperature whereas catalysts obtained on MaTeck supports are not active at those conditions. In turn, catalysts based on MaTeck support are more active in temperature range 420-700 K. The different activities are attributed to difference in average crystallite sizes and in support morphology.

• Publisher: Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
• Journal: Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
• Year: 2011
• Volume: 66
• Pages: 37-46

Dates

published

1 - 1 - 2011

online

19 - 12 - 2011

Contributors

author

R. Wróbel

• Institute of Organic Chemical Technology, West Pomeranian University of Technology

author

S. łagonda

• Institute of Organic Chemical Technology, West Pomeranian University of Technology

author

U. Narkiewicz

• Institute of Organic Chemical Technology, West Pomeranian University of Technology

author

R. Pełech

• Institute of Organic Chemical Technology, Institute of Chemical and Environment Engineering, Pulaskiego 10, 70-322 Szczecin, Poland

author

S. Becker

• Chemisches Institut, Otto-von-Guericke Universität, Universitätsplatz 2, 39106 Magdeburg, Germany

author

L. Szymaszkiewicz

• Szczecin University, Institute of Mathematics, Wielkopolska 15, 70-451 Szczecin, Poland

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Identifiers

DOI

10.2478/v10063-011-0005-y