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Number of results
2012 | 14 | 4 | 19-21

Article title

Bromine catalyst for the methane to methyl bisulfate reaction


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A catalytic system KBr - oleum is effective at catalyzing the selective oxidation of methane to methanol via. methyl bisulfate. The influences of methane pressure, sulfur trioxide and temperature on turnover frequency were investigated.










Physical description


1 - 12 - 2012
12 - 01 - 2013


  • West Pomeranian University of Technology, Szczecin, ul. Pułaskiego 10, 70-322 Szczecin, Poland
  • West Pomeranian University of Technology, Szczecin, ul. Pułaskiego 10, 70-322 Szczecin, Poland


  • 1. Mukhopadhyay, S. & Bell, A.T. (2003) Direct catalytic sulfonation of methane with SO2 to methanesulfonic acid (MSA) in the presence of molecular O2. Chem. Commun. 1590-1591. DOI: 10.1039/b303561a.[Crossref]
  • 2. Kao, L-C, Hutson, A.C. & Sen, A. (1991) Low temperature, palladium(II)-catalyzed, solution-phase oxidation of methane to methanol derivative. J. Am. Chem. Soc. 113, 700-701. DOI: 10.1021/ja00002a063.[Crossref]
  • 3. Periana, R.A.,. Taube, D.J, Evitt, E.R., Löffle,r D.G., Wentrcek, P.R, Voss, G. & Masuda, T. (1993) A Mercury-Catalyzed, High-Yield System for the Oxidation of Methane to Methanol. Science 259, 340.-343. DOI: 10.1126/science.280.5363.493f.[Crossref]
  • 4. Sen, A., Benvenuto, M.A., Lin, M.,. Hutson, A.C. & Basickes, N. (1994) Activations of Methane and Ethane and Their Selective Oxidation to the Alcohols in Protic Media. J.Am. Chem. Soc. 116, 998-1003. DOI: 10.1021/ja00082a022.[Crossref]
  • 5. Periana, R.A., Taube, D.J., Gamble, S., Taube, H., Satoh, T. & Fujii, H. (1998) Platinum Catalysts for the High-Yield Oxidation of Methane to a Methanol Derivative. Science 280, 560-564. DOI: 10.1126/science.280.5363.560.[Crossref]
  • 6. Gang, X., Birch, H., Zhu, Y., Hjuler, H.A. & Bjerrum, N.J. (2000) Direct Oxidation of Methane to Methanol by Mercuric Sulfate Catalyst. J. Catal. 196, 287-292. DOI: 10.1006/jcat.2000.3051.[Crossref]
  • 7. Michalkiewicz, B., Kałucki, K. & Sośnicki, J.G. (2003) Catalytic system containing metallic palladium in the process of methane partial oxidation. J. Catal. 215, 14-19. DOI: 10.1016/S0021-9517(02)00088-X.[Crossref]
  • 8. Michalkiewicz, B. (2006) The kinetics of homogeneous catalytic methane oxidation. Appl. Catal. A. 307, 270-274. DOI: 10.1016/j.apcata.2006.04.006.[Crossref]
  • 9. Cheng, J., Li, Z., Haught, M. & Tang, Y. (2006) Direct methane conversion to methanol by ionic liquid- -dissolved platinum catalysts. Chem. Commun. 4617-4619. DOI: 10.1039/b610328f.[Crossref]
  • 10. Gang, X., Zhu, Y., Birch, H., Aage, H., Hjuler, A. & Bjerrum, N. (2004) Iodine as catalyst for the direct oxidation of methane to methyl sulfates in oleum. Appl. Catal. A. 261, 91-98. DOI: 10.1016/j.apcata.2003.10.039.[Crossref]
  • 11. Periana, R. A., Mirinov, O., Taube, D. J. & Gamble, S. (2002) High yield conversion of methane to methyl bisulfate catalyzed by iodine cations. Chem. Commun. 2376-2377. DOI: 10.1039/B205366G.[Crossref]
  • 12. Jarosińska, M., Lubkowski, K., Sośnicki, J.G. & Michalkiewicz, B. (2008) Application of Halogens as Catalysts of CH4 Esterification. Catal. Lett. 126, 407-412. DOI 10.1007/s10562-008-9645-8.[WoS]
  • 13. Gillespie, R.J. & Morton, M.J., (1971) Halogen and interhalogen cations. Quart. Rev. 25, 553-559 DOI: 10.1039/ QR9712500553.[Crossref]
  • 14. Greenwood, N.N., Earnshaw, A. (1987) Chemistry ofthe Elements, Butterworth-Heinemann Oxford and references therein.

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