Utilization of the post - filtration lye from the soda-chlorine-saltpetre method of soda production

• Authors: Sebastian Drużyński , Mieczysław Trypuć , Urszula Kiełkowska , Krzysztof Mazurek
• Languages of publication: EN

Abstracts

EN

The optimal conditions were determined for the precipitation of ammonium metavanadate from the solutions of ammonium nitrate with the use of sodium metavanadate. The experiments were performed with the molar ratio of salts NH4NO3: NaVO3 1.5:1 at temperatures 293, 303, 313 and 323 K. Based on the obtained results, the optimal time of the process was determined as 5 h at 293-303K. Under these conditions, the achieved yield of the precipitation process was ~98.7%, while the contents of the vanadium salts in the post - filtration solution was ~0.02%.

Keywords

EN

SCS method; double exchange; ammonium nitrate and ammonium metavanadate

• Publisher: De Gruyter Open
• Journal: Polish Journal of Chemical Technology
• Year: 2011
• Volume: 13
• Issue: 4
• Pages: 53-56

Dates

published

1 - 1 - 2011

online

2 - 1 - 2012

Contributors

author

Sebastian Drużyński

• Faculty of Chemistry, Department of Chemical Technology, Nicolaus Copernicus University, Gagarina 7, 87-100 Toruń, Poland

author

Mieczysław Trypuć

• Faculty of Chemistry, Department of Chemical Technology, Nicolaus Copernicus University, Gagarina 7, 87-100 Toruń, Poland

author

Urszula Kiełkowska

• Faculty of Chemistry, Department of Chemical Technology, Nicolaus Copernicus University, Gagarina 7, 87-100 Toruń, Poland

author

Krzysztof Mazurek

• Faculty of Chemistry, Department of Chemical Technology, Nicolaus Copernicus University, Gagarina 7, 87-100 Toruń, Poland

References

• Collaborative paper (1969). Research on the new method of soda production. Nicolaus Copernicus University Publishers, Toruń.
• Kołaczkowski, A. (1980). Spontaneous decomposition of ammonium nitrate. Scientific Papers, Institute of Inorganic Technology and Mineral Fertilizers, Wrocław Technical University Publishers.
• Bobrownicki, W., Biskupski, A. & Kołaczkowski, A. (1977). On the thermal decomposition of ammonium-sodium nitrate. Applied Chemistry, 21, 3-18.
• Trypuć, M. & Łyjak, G. (2001). Application of NaVO3 for the utilization of the after-filtration liquor from Solvay's process. Ind. & Eng. Chem. Res. 40, 2188-2192. DOI: 10.1021/ie000965r.[Crossref]
• Trypuć, M. & Łyjak, G. (2000). Solubility investigations in the NH4Cl + NaVO3 + NH4VO3 + NaCl + H2O system at 303K. J. Chem. Eng. Data, 45, 872-875. DOI: 10.1021/je000091f.[Crossref]
• Trypuć, M., Drużyński, S. & Mazurek, K. (2008). Plotting of the solubility isotherm for the NH4NO3 + NaVO3 + H2O system. Pol. J. Chem. Tech., 10(4), 11-14. DOI: 10.2478/v10026-008-0039-x.[Crossref]
• Trypuć M. & Drużyński S. (2009). Phase diagram for the NH4NO3 + NaVO3 + NH4VO3 + NaNO3 + H2O system at 293 and 303 K. Ind. & Eng. Chem. Res. 48, 6937-6942. DOI: 10.1021/ie9004139.[Crossref]
• Struszyński, M. (1957). Analiza ilościowa i techniczna (vol I). Polish Scientific Publishers, Warsaw.
• Williams, W.J. (1985). Oznaczanie anionów. Polish Scientific Publishers, Warsaw.
• Sandell, E.B. (1961). Colorimetric determination of traces of metals. Interscience Publishers Inc., New York.
• Schaeppi, Y. & Treadwell, W.D. (1948). Über die kolorimetrische Bestimmung der Stöchiometrie einiger Farb-komplexe" Hel. Chim. Acta, 31, 577-588.[Crossref]
• Trypuć, M. & Drużyński, S. (2007). Investigation of the solubility in the NaVO3 - NaNO3 - H2O system. Ind. & Eng. Chem. Res. 46, 2688-2692. DOI: 10.1021/ie0614125.[Crossref]
• Trypuć, M., Drużyński, S., Kiełkowska, U. & Mazurek, K. (2007). Utilization of the post - filtration lye from the SCS method of soda production" Pol. J. Chem. Tech. 9(4), 59-62. DOI: 10.2478/v10026-007-0091-y.[Crossref]

Identifiers

DOI

10.2478/v10026-011-0049-y