Full-text resources of PSJD and other databases are now available in the new Library of Science.
Visit https://bibliotekanauki.pl

PL EN


Preferences help
enabled [disable] Abstract
Number of results
2011 | 13 | 3 | 42-46

Article title

Polyetherols from melamine cyanurate and ethylene carbobate - synthesis and application

Content

Title variants

Languages of publication

EN

Abstracts

EN
The results of the study on the reactions of melamine cyanurate with ethylene carbonate were presented. As a result of the reactions, polyetherols containing thermostabile 1,3,5-triazine and perhyroxo-1,3,5-triazine rings in their structure were obtained. Basic physical properties such as density, viscosity, hydroxyl number, weight changes were measured. The polyetherols were applied as a polyol component to receiving of thermoresistant polyurethane foams. Some of the properties of the obtained foams were investigated. The value of the apparent density is between 51 and 71 kg/m3, compressive strength 222-356 kPa and the content of the open pores between 14-33%. Thermal resistance was also studied by means of the TGA method. It was found that oxygen index of the selected compositions is between 20-22%.

Publisher

Year

Volume

13

Issue

3

Pages

42-46

Physical description

Dates

published
1 - 1 - 2011
online
5 - 10 - 2011

Contributors

  • Department of Polyester, Epoxides and Polyurethanes, Industrial Chemistry Research Institute, ul. Rydygiera 8, 01-793 Warszawa, Poland
  • Department of Polyester, Epoxides and Polyurethanes, Industrial Chemistry Research Institute, ul. Rydygiera 8, 01-793 Warszawa, Poland

References

  • Casu, A., Camino, G., De Giorgi, M., Flath, D., Morone, V., Zenoni, R., Fire-retardant mechanistic aspects of melamine cyanurate in polyamide copolymer. Polym. Degrad. Stab., 58 (1997), 297-302, DOI:10.1016/S0141-3910(97)00061-X.[Crossref]
  • Roland, W., Reinhard, B., Andreas, D. (2007). EP No. 1731559. European Patent Office.
  • Morival, G., Hervy, C. (1988). US Patent No. 4786673. Washington, D.C.: U.S. Patent and Trademark Office.
  • Kasowski, R., Martens, M. (2000). US Patent No. 3,025,419. Washington, D.C.: U.S. Patent and Trademark Office.
  • Modesti, M., Lorenzetti, A., Simioni, F. and Checchin, M. (2001). Influence of different flame retardants on fire behaviour of modified PIR/PUR polymers. Polym. Degrad. Stab. 74(3), 475-479, DOI:10.1016/S0141-3910(01)00171-9.[Crossref]
  • Zatorski, W., Brzozowski, Z. (2003). Pol. Patent No. 198605. Warsaw, Patent Office of The Republic of Poland.
  • Mazo, G.Y., Ross, R.J., Kneller, J.F., Mazo, J. (1999). U.S. Patent No. 5,939,517. Washington, D.C.: U.S. Patent and Trademark Office.
  • Klimiec, J., Fabisz, E., Researches on synthesis of propylene carbonate. Chem. Ind. 79 (10) 339-340 2000.
  • Clements, J.H. Reactive Applications of Cyclic Alkylene Carbonates. Ind. Eng. Chem. Res. (2003). 42 (4), pp 663-674, DOI: 10.1021/ie020678i.[Crossref]
  • Kowalski, P. (2004). Laboratory of Organic Chemistry; WNT: Warsaw, (in Polish).
  • Kocot-Bończak, D. (1977). Laboratory Experiments in Physical Chemistry PZWL: Warsaw, (in Polish).
  • Polish Committee for Standardization (1993). Polish Standards: Polyethers for polyurethanes - Test methods-Determination of hydroxyl number. PN-C-89052-03: Method A. Poland.
  • Polish Committee for Standardization (1999). Polish (European) Standards: Products for thermal insulation for building - Determination of apparent density. PN-EN 1602. Poland.
  • Polish Committee for Standardization (1998). Polish (European) Standards: Products for thermal insulation for building - Determination of behavior during compression. PN-EN 826. Poland.
  • Polish Committee for Standardization (2005). Polish Standards: Rigid porous plastics - Determination of percentage volumetric content of open and closed cells. PN-ISO 4590. Poland.
  • Polish Committee for Standardization (2006). Polish (European) Standards: Plastics - Determination of flammability by oxygen index - Part 2: Test at room temperature. PNEN ISO 4589-2. Poland.
  • Mc Entire, E.E., Gipson, R.M. (1981). U.S. Patent No. 4 265 821 Washington, D.C.: U.S. Patent and Trademark Office.

Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_v10026-011-0035-4
JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.