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2010 | 12 | 2 | 1-3
Article title

Oxidation of hexafluoropropylene to hexafluoropropylene oxide using oxygen

Content
Title variants
Languages of publication
EN
Abstracts
EN
A method for pressure oxidation of hexafluoropropylene (HFP) to hexafluoropropylene oxide (HFPO), using oxygen, is presented. Oxidation was achieved in a batch-fed reactor at temperature range between 130 to 170°C. The influence of temperature and kind of solvents, such as 1,2,2-trichloro-1,1,2-trifluoroethane (CFC-113) and carbon tetrachloride on the yield of HFPO and the course of oxidation was investigated in preliminary studies. The maximum HFPO yield of approximately 83% was noticed.
Publisher
Year
Volume
12
Issue
2
Pages
1-3
Physical description
Dates
published
1 - 1 - 2010
online
9 - 7 - 2010
References
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  • Meissner, E. & Wróblewska, A. (2007). Oxidation of hexafluoropropylene with molecular oxygen. Polish J. Chem. Technol. 9 (1), 20-22. DOI: 10.2478/v10026-007-0006-y.[Crossref]
  • Meissner, E. & Wróblewska, A. (2006). Oxidation of hexafluoropropylene using hydrogen peroxide in the presence of phase transfer catalyst. Polish J. Chem. Technol. 8(2), 66-67.
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  • Eleuterio, H. S. & Meschke, R. W. (1967). Fluorocarbon epoxides. US Pat. 3358003.
  • Gilbert, J. R., Slagle, I. R., Graham, R. E. & Gutman, D. (1976). Direct identification of reactive routes and measurement of rate constants in the reactions of oxygen atoms with the fluoroethylenes. J. Phys. Chem. 80 (1), 14-18. DOI: 10.1021/j100542a003.[Crossref]
Document Type
Publication order reference
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_v10026-010-0009-y
Identifiers
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