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Number of results
2010 | 12 | 2 | 1-3

Article title

Oxidation of hexafluoropropylene to hexafluoropropylene oxide using oxygen

Content

Title variants

Languages of publication

EN

Abstracts

EN
A method for pressure oxidation of hexafluoropropylene (HFP) to hexafluoropropylene oxide (HFPO), using oxygen, is presented. Oxidation was achieved in a batch-fed reactor at temperature range between 130 to 170°C. The influence of temperature and kind of solvents, such as 1,2,2-trichloro-1,1,2-trifluoroethane (CFC-113) and carbon tetrachloride on the yield of HFPO and the course of oxidation was investigated in preliminary studies. The maximum HFPO yield of approximately 83% was noticed.

Publisher

Year

Volume

12

Issue

2

Pages

1-3

Physical description

Dates

published
1 - 1 - 2010
online
9 - 7 - 2010

Contributors

  • Institute of Organic Chemical Technology, West Pomeranian University of Technology Szczecin, ul. Pulaskiego 10, 70-322 Szczecin, Poland
  • Institute of Organic Chemical Technology, West Pomeranian University of Technology Szczecin, ul. Pulaskiego 10, 70-322 Szczecin, Poland

References

  • Fittes, D. W., Griffiths, D. J. & Nash, P. (1969). The use of light water for major aircraft fires. Fine Technology 5 (4), 284-298. DOI: 10.1007/BF02600416.[Crossref]
  • Millauer, H. (1977). Process for the preparation of hexafluoropropylene epoxide. US Pat. 4014762.
  • Hill, J. T., Garabedian, M. E. (1972). Process for preparing fluorine-containing polymers. US Pat. 3660315.
  • Atkins, G. (1973). Process for the epoxidation of hexafluoropropylene. US Pat. 3775439.
  • Ikeda, M., Miura, M. & Aoshima, A. (1990). Process for the production of hexafluoropropylene oxide. US Pat. 4902810.
  • Meissner, E. & Wróblewska, A. (2007). Oxidation of hexafluoropropylene with molecular oxygen. Polish J. Chem. Technol. 9 (1), 20-22. DOI: 10.2478/v10026-007-0006-y.[Crossref]
  • Meissner, E. & Wróblewska, A. (2006). Oxidation of hexafluoropropylene using hydrogen peroxide in the presence of phase transfer catalyst. Polish J. Chem. Technol. 8(2), 66-67.
  • Carlos, D. P. (1970). Method for the preparation of halogenated epoxides. US Pat. 3536733.
  • Eleuterio, H. S. & Meschke, R. W. (1967). Fluorocarbon epoxides. US Pat. 3358003.
  • Gilbert, J. R., Slagle, I. R., Graham, R. E. & Gutman, D. (1976). Direct identification of reactive routes and measurement of rate constants in the reactions of oxygen atoms with the fluoroethylenes. J. Phys. Chem. 80 (1), 14-18. DOI: 10.1021/j100542a003.[Crossref]

Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_v10026-010-0009-y
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