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Number of results
2009 | 11 | 2 | 1-5
Article title

New closure method for a simultaneous diazo coupling between 1- and 2-Naphthols and diazotized sulphanilic acid

Content
Title variants
Languages of publication
EN
Abstracts
EN
This paper presents the effects of mixing on the course of complex chemical reactions in relation to the manufacturing of pure products at high reaction selectivity, and designing mixing strategies using complex, homogeneous test reaction systems. As an example, the competitive-consecutive and parallel reaction test system including a simultaneous diazo-coupling between 1- and 2-naphtols and diazotized sulphanilic acid is considered. The effect of mixing on the reaction selectivity is interpreted using mechanistic modeling and a new closure scheme. The new closure represents an extension of the conditional PDF closure applied before to simple reaction schemes.
Publisher

Year
Volume
11
Issue
2
Pages
1-5
Physical description
Dates
published
1 - 1 - 2009
online
19 - 6 - 2009
Contributors
  • Faculty of Chemical and Process Engineering, Warsaw University of Technology, ul. Waryńskiego 1, 00-645 Warszawa, Poland
  • Faculty of Chemical and Process Engineering, Warsaw University of Technology, ul. Waryńskiego 1, 00-645 Warszawa, Poland
References
  • Bałdyga, J. & Bourne, J.R. (1999). Turbulent mixing and chemical reactions. Chichester: Wiley.
  • Bałdyga, J., Henczka, M. & Makowski, ł. (2001). Effects of mixing on parallel chemical reactions in a continuousflow stirred-tank reactor. Trans IChemE. 79, 895-900. DOI: 10.1205/02638760152721109[Crossref]
  • Bałdyga, J., Kowalski, A., Cooke, M. & Jasińska, M. (2007). Investigations of micromixing in a rotor-stator mixer. Chemical and Proces Engineering. 28, 867-877.
  • Bourne, J.R., Kut, O.M., Lenzner, J. & Maire, H. (1990). Kinetics of diazo coupling between 1-naphtol and diazotized sulphanilic acid. Ind. Eng. Chem. Res., 29, 1761-1765. DOI: 10.1021/ie00105a004[Crossref]
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_v10026-009-0016-z
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