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Number of results
2007 | 9 | 4 | 111-114

Article title

Preparation methods of calcium sulphate and urea adduct

Content

Title variants

Languages of publication

EN

Abstracts

EN
The paper presents the results of laboratory studies on the preparation of calcium sulphate and urea adduct by: grinding, compacting and mixing in the presence of physical water. A method for the measurement of urea conversion into the adduct form, which is based on the difference in solubility of free urea and the adduct bound urea CaSO4·4CO(NH2)2 in n-butanol, was developed. Mixing the reagents in the presence of physical water produced the best results. High urea conversion into the adduct form, over 85%, in the prepared samples indicates that this method can be successfully used to get CaSO4·4CO(NH2)2 adduct.

Keywords

Publisher

Year

Volume

9

Issue

4

Pages

111-114

Physical description

Dates

published
1 - 12 - 2007
online
30 - 1 - 2008

Contributors

  • The State Higher Vocational School, ul. Grodzka 19, 48-300 Nysa, Poland
  • Institute of Inorganic Technology and Mineral Fertilizers, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland
  • Institute of Inorganic Technology and Mineral Fertilizers, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

References

  • Tengler S.: Niektóre międzycząsteczkowe połączenia mocznika ze związkami nieorganicznymi, Chemik, 1972, 8, 308.
  • Durski Z.: Krystaliczne addukty mocznika ze związkami nieorganicznymi, Wiadomości. Chemiczne, 1971, 25, 829.
  • Whittaker C., Lundstom F., Hendricks S.: Reaction between urea and gypsum, Industrial & Engineering Chemistry, 1933, 11, 1280.
  • Achard P., Schwob Y., Limousin L.: A new route for urea-superphosphate fertilizers, Phosphorus & Potassium, 1994, 191, 27.
  • Patent USA 2074880, 1937.
  • Nagai S., Hara Z.: Studies on gypsum - urea or urea - calcium sulphate complex I, Journal of Society Chemical Industry Japan, Suppl. Bind., 1939, 42, 210.
  • Nagai S., Miyake R., Studies on gypsum - urea or urea - calcium sulphate complex II, Journal of Society Chemical Industry Japan, Suppl. Bind., 1940, 43, 209.
  • Kotuła E., Nowak R.: Czteromocznikan siarczanu wapnia - nawóz azotowo-siarkowo-wapniowy jako alternatywa utylizacji fosfogipsu, Prace Nauk. Politechniki Szczecińskiej, 1998, 547, ITN 5, 91.
  • Maciaszek, S.: Mocznik, WNT, Warszawa 1967.[PubMed]
  • Patent USA 3976467, 1976.

Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_v10026-007-0102-z
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