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2007 | 9 | 3 | 105-107
Article title

Optimization of the epoxidation process of (1Z,5E,9E)-1,5,9-cyclododecatriene to 1,2-epoxy-(5Z,9E)-5,9-cyclododecadiene with tert-buthyl hydroperoxide - the influence of technological parameters on the hydroperoxide conversion

Content
Title variants
Languages of publication
EN
Abstracts
EN
The optimization studies of the epoxidation process of (1Z,5E,9E)-1,5,9-cyclododecatriene (CDT) with tert-buthyl hydroperoxide (TBHP) over the molybdenum catalyst Mo(CO)6 were performed. The reaction was examined in terms of a uniform-rotatable design. Three factors were analyzed: the reaction time, CDT:TBHP molar ratio, and the molar concentration of the catalyst (Mo(CO)6). According to the design 20 experiments were performed at the constant temperature of 70°C.
Publisher
Year
Volume
9
Issue
3
Pages
105-107
Physical description
Dates
published
1 - 1 - 2007
online
6 - 11 - 2007
References
  • Kirk-Othmer Encyclopedia of Chemical Technology, Vol. 9, 4th ed., Wiley, New York, 1991.
  • Arends I. W. C. E., Sheldon R. A.: Recent developments in selective catalytic epoxidations with H2O2, Topics in Catalysis, 2002, 19, 133.[Crossref]
  • Sheldon R. A., In. Ugo R. (Ed.): Aspects of Homogenous Catalysis, Vol. 4, Reidel, Dordrecht, 1981.
  • Polański Z.: Metodyka badań doświadczalnych, Kraków 1984.
Document Type
Publication order reference
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_v10026-007-0066-z
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