Epoxidation of 2-buten-1-ol over Ti-MCM-41 and Ti-MCM-48 titanium silicalite catalysts

• Authors: Agnieszka Wróblewska , Ewelina Ławro , Eugeniusz Milchert
• Languages of publication: EN

Abstracts

EN

The results of the epoxidation of 2-buten-1-ol with 30 wt% hydrogen peroxide have been presented. As a solvent methanol was used. The process was carried out over the titanium silicalite catalysts: Ti-MCM-41 and Ti-MCM-48. The influence of temperature (20 - 120°C), the molar ratio of CRA/H2O2 (5:1 - 5:1), methanol concentration (5 - 90 wt%), catalyst concentration (0.1 - 5.0 wt%) and the reaction time (30 - 300 min) was investigated. The obtained results were used for the determination of optimum conditions of running the epoxidation process of 2-buten-1-ol.

Keywords

EN

epoxidation; 2,3-epoxybutan-1-ol; Ti-MCM-41; Ti-MCM-48

• Publisher: De Gruyter Open
• Journal: Polish Journal of Chemical Technology
• Year: 2007
• Volume: 9
• Issue: 3
• Pages: 1-4

Dates

published

1 - 1 - 2007

online

6 - 11 - 2007

Contributors

author

Agnieszka Wróblewska

• Faculty of Technology and Chemical Engineering, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

author

Ewelina Ławro

• Faculty of Technology and Chemical Engineering, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

author

Eugeniusz Milchert

• Faculty of Technology and Chemical Engineering, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

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Identifiers

DOI

10.2478/v10026-007-0041-8