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Number of results
2007 | 9 | 3 | 1-4

Article title

Epoxidation of 2-buten-1-ol over Ti-MCM-41 and Ti-MCM-48 titanium silicalite catalysts

Content

Title variants

Languages of publication

EN

Abstracts

EN
The results of the epoxidation of 2-buten-1-ol with 30 wt% hydrogen peroxide have been presented. As a solvent methanol was used. The process was carried out over the titanium silicalite catalysts: Ti-MCM-41 and Ti-MCM-48. The influence of temperature (20 - 120°C), the molar ratio of CRA/H2O2 (5:1 - 5:1), methanol concentration (5 - 90 wt%), catalyst concentration (0.1 - 5.0 wt%) and the reaction time (30 - 300 min) was investigated. The obtained results were used for the determination of optimum conditions of running the epoxidation process of 2-buten-1-ol.

Publisher

Year

Volume

9

Issue

3

Pages

1-4

Physical description

Dates

published
1 - 1 - 2007
online
6 - 11 - 2007

Contributors

  • Faculty of Technology and Chemical Engineering, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland
  • Faculty of Technology and Chemical Engineering, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland
  • Faculty of Technology and Chemical Engineering, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

References

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  • Anderson M.: Simplified description of MCM-48, Zeolites, 1997, 19, 220.
  • Kumar D., Schumacher K, Hohenesche C. F., Grün M., Unger K.: MCM-41, MCM-48 and related mesoporous adsorbents: their synthesis and characterization, Coll. Surf. A: Phys. Eng. Aspects, 2001, 187 - 188, 109.
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  • Shao H., Zhu Q., Goodman M.: A New Asymmetric Synthesis of .alpha.-Methylcysteines via Chiral Aziridines, J. Org. Chem., 1995, 60, 790.
  • Grün M., Unger K. K., Matsumoto A., Tsutsumi K.: Novel pathways for the preparation of mesoporous MCM-41 materials: control of porosity and morphology, Microporous and Mesoporous Materials, 1999, 27, 207.
  • Schumacher K., Grün M., Unger K. K.: Novel synthesis of spherical MCM-48, Microporous and Mesoporous Materials, 1999, 27, 201.

Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_v10026-007-0041-8
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