The pressure method of 1-butene-3-ol epoxidation over Ti-beta catalyst

• Authors: Agnieszka Wróblewska , Joanna Wajzberg , Eugeniusz Milchert , Barbara Grzmil , Janusz Ziebro
• Languages of publication: EN

Abstracts

EN

The investigations of 1-buten-3-ol (1B3O) epoxidation by 30% hydrogen peroxide over Ti-Beta catalyst were performed. The experiments were carried out under the autogenic pressure and at the presence of methanol as a solvent. The influence of the following technological parameters on the course of epoxidation: temperature (20 - 120°C), the molar ratio of 1B3O/H2O2 (0.5:1 - 5:1), methanol concentration (5 - 90 wt%.), Ti-Beta concentration (0.1 - 5.0 wt%) and the reaction time (0.5 - 5.0 h) was investigated. The main functions describing the process were: the selectivity of transformation to 1,2-epokxy-3-butanol in relation to 1B3O consumed, conversions of substrates as well as the selectivity of transformation to organic compounds in relation hydrogen peroxide consumed.

Keywords

EN

liquid phase epoxidation; 1,2-epoxy-3-butanol; Ti-Beta catalyst

• Journal: Polish Journal of Chemical Technology
• Year: 2007
• Volume: 9
• Issue: 2
• Pages: 53-56

Dates

published

1 - 1 - 2007

online

19 - 10 - 2007

Contributors

author

Agnieszka Wróblewska

• Institute of Organic Chemical Technology, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

author

Joanna Wajzberg

• Institute of Organic Chemical Technology, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

author

Eugeniusz Milchert

• Institute of Organic Chemical Technology, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

author

Barbara Grzmil

• Institute of Inorganic Chemical Technology, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

author

Janusz Ziebro

• Institute of Inorganic Chemical Technology, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

References

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Identifiers

DOI

10.2478/v10026-007-0026-7