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Number of results
2007 | 9 | 2 | 49-52

Article title

The new method of 1,2-epoxy-3-butanol production over titanium silicalite catalysts

Content

Title variants

Languages of publication

EN

Abstracts

EN
The results of 1-butene-3-ol (1B3O) epoxidation over the titanium silicalite catalysts: TS-1, Ti-Beta, Ti-MCM-41 has been presented. The optimal parameters obtained for the individual catalyst were compared. The main functions describing the process were: the selectivity of transformation to 1,2-epoxy-3-butanol (1,2E3B) in relation to 1B3O consumed, the conversions of 1B3O and hydrogen peroxide and the selectivity of the transformation to organic compounds in relation to the H2O2 consumed. The main product of the epoxidation process was 1,2-epoksy-3-butanol, the chemical compounds having a lot of applications.

Publisher

Year

Volume

9

Issue

2

Pages

49-52

Physical description

Dates

published
1 - 1 - 2007
online
19 - 10 - 2007

Contributors

  • Institute of Organic Chemical Technology, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland
  • Institute of Organic Chemical Technology, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

References

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  • Thangaraj A., Kumar R., Ratnasamy P.: Direct catalytic hydroxylation of benzene with hydrogen peroxide over titanium-silicalite zeolites, Appl. Catal., 1990, 57, L1-L3.
  • Camblor M. A., Corma A., Martinez A., Perez-Pariente J.: Synthesis of a titaniumsilicoaluminate isomorphous to zeolite beta and its application as a catalyst for the selective oxidation of large organic molecules, J. Chem. Soc., 1992, 8, 589.
  • Grün M., Unger K. K, Matsumoto A., Tatsumi K.: Novel pathways for the preparation of mesoporous MCM-41 materials: control of porosity and morphology, Micropor. Mesopor. Mater.27, 1999, 207.
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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_v10026-007-0025-8
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