PL EN


Preferences help
enabled [disable] Abstract
Number of results
2014 | 69 | 1-2 | 111-126
Article title

Thermal behaviour of light lanthanide(III) complexes with 2,3-pyridinedicarboxylic acid

Content
Title variants
Languages of publication
EN
Abstracts
EN
The lanthanide(III) complexes with 2,3-pyridinedicarboxylate ligand (PDC) were obtained as crystalline compounds from the water solutions. These compounds form the series of Ln2(PDC)3 ・ nH2O. All compounds are stable in air and insoluble in both water and common organic solvents. The hydrated complexes have been characterized by elemental analysis, thermal analysis (TG/DSC/DTA, and TG−FT-IR), FT-IR spectroscopy and X-ray analysis. 2,3-pyridinedicarboxylates of lanthanides(III) are stable in air below 313−323 K. Upon heating, hydrated complexes lose crystallization and lattice water in two steps. The values of dehydration enthalpy complexes are calculated from the DSC curves. The anhydrous compounds are stable at the temperature from 473 K to about 623 K and when heated they decompose to lanthanide oxides. Thermal and spectroscopic studies are essential for further studies and classification of compounds as MOF-like structures.
Publisher

Year
Volume
69
Issue
1-2
Pages
111-126
Physical description
Dates
published
2014-12-01
online
2014-12-30
Contributors
  • Department of General and Coordination Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska University, M. Curie-Skłodowska Sq. 2, 20-031 Lublin, Poland, z.rzaczynska@poczta.umcs.lublin.pl
  • Department of General and Coordination Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska University, M. Curie-Skłodowska Sq. 2, 20-031 Lublin, Poland
  • Central Laboratory, Faculty of Chemistry, Maria Curie-Skłodowska University, M. Curie-Skłodowska Sq. 3, 20-031 Lublin, Poland
References
  • [1] U. Ravon, M. Savonnet, S. Aguado, M.E. Domine, E. Janneau, D. Ferrusseng, Microporous Mesoporous Mater., 129, 319, (2010).
  • [2] A. Szorcsik, L. Nagy, A. Deak, M. Scopelliti, Z.A. Fekate, A. Csaszar, C. Pellerito, L. Pellerito, J. Organomet. Chem., 689, 2762, (2004).
  • [3] L.K. Hou, F.Y. Bai, Y.H. Xing, Y.Z. Cao, D.M. Wei, S.Y. Niu, J. Inorg. Organomet. Polym., 10.10007/s10904-010-9441-y, (2010).
  • [4] C. Qin, X. Wang, E. Wang, L. Xu, Inorg. Chim. Acta, 359, 417, (2006).
  • [5] A. Szorcsik, L. Nagy, J. Sletten, G. Szalontai, E. Kamu, T. Fiore, L. Pellerito, E. Kalman, J. Organomet. Chem., 689, 1145, (2004).
  • [6] X. Gu, D. Xue, H. Ratajczak, J. Mol. Struct., 887, 56, (2008).
  • [7] S.Q. Xia, S. Hu, J.C. Dai, T.X. Wu, J.J. Zhang, Z.Y. Fu, W.X. Du, Inorg. Chem. Commun., 7, 51, (2004).
  • [8] X. Zhu, S. Gao, Y. Li, H. Yang, G. Li, B. Xu, R. Cao, J. Solid State Chem., 182, 421, (2009).
  • [9] Z. Hnatejko, G. Dutkiewicz, M. Kubicki, S. Lis, J. Mol. Struct., 1034, 128, (2013).
  • [10] J.C. Yao, J.B. Guo, J.G. Wang, Y.F. Wang, L. Zhang, C.P. Fan, Inorg. Chem. Commun., 13, 1178, (2010).
  • [11] Y.S. Song, B. Yan, Z.X. Chen, Inorg. Chim. Acta, 360, 3431, (2007).
  • [12] X. Wang, C. Qin, E. Wang, Y. Li, N. Hao, C. Hu, L. Xu, Inorg. Chem., 43, 1850, (2004).
  • [13] A. Kvick, T.F. Koetzle, R. Thomas, F. Tukusagawa, J. Chem. Phys., 60, 3866, (1974).
  • [14] K.M. Harmon, K.E. Shaw, J. Mol. Struct., 513, 219, (1999).
  • [15] H. Briehl, J. Butenuth, Thermochim. Acta, 211, 121, (1992).
  • [16] H. Briehl, J. Butenuth, Thermochim. Acta, 167, 249, (1990).
  • [17] L. Campanella, T. Ferri, P. Mozzani, J. Inorg. Nucl. Chem., 41, 1054, (1979).
  • [18] K.M. Harmon, P.W. Brown, S.H. Gill, J. Mol. Struct., 448, 43, (1998)
  • [19] B. Barszcz, M. Hodorowicz, A. Jabłońska-Wawrzycka, J. Masternak, W. Nitek, K. Stadnicka, Polyhedron, 29, 1193, (2010).
  • [20] Y. Kang, J. Zhang, Z.J. Li, J.K. Cheng, Y.G. Yao, Inorg. Chim. Acta, 59, 2201, (2006).
  • [21] M.A.S. Goher, A.A. Youssef, Z-Y. Zhou, T.C.W. Mak, Polyhedron, 12, 1871, (1993).
  • [22] Z.T. Yu, G.H. Li, Y.S. Jiang, J.J. Xu, J.S. Chen, Dalton Trans., 4219 (2003).
  • [23] Z.T. Yu, Z.L. Liao, Y.S. Jiang, Chem. Commun., 1814 (2004).
  • [24] C.X. Zhang, C.B. Ma, M. Wang, C.N. Chen, Chin. J. Struct. Chem., 27, 1370, (2008).
  • [25] L.J. Li, Y. Li, J. Mol. Struct., 694, 199, (2004).
  • [26] M.A.S. Goher, A.A. Youssef, F.A. Mautner, Polyhedron, 25, 1531, (2006).
  • [27] M.G.B. Drew, R.W. Matthews, R.A. Walton, J. Chem. Soc. A, 2959, (1971).
  • [28] B.O. Patrick, C.L. Stevens, A. Storr, Polyhedron, 22, 3025, (2003).
  • [29] F. Jaber, F. Charbannier, R. Faure, Polyhedron, 15, 2909, (1996).
  • [30] Q. Yue, J. Yang, G.H. Li, G.D. Li, W. Xu, J.S. Chen, S.N. Wang, Inorg. Chem., 44, 5241, (2005).
  • [31] S.A. Cotton, CR Chimie, 8, 129, (2005).
  • [32] P. Mahata, G. Sankar, G. Madras, S. Natarajan, Chem. Commun., 5787 (2005), [33] W. Brzyska, W. Ożga, J. Therm. Anal. Calorim., 288, 113, (1996).
  • [34] W. Brzyska, W. Ożga, J. Therm. Anal. Calorim., 273, 205, (1996).
  • [35] Z. Rzączyńska, A. Danczowska-Burdon, J. Therm. Anal. Calorim., 108, 991, (2012).
  • [36] Z. Rzączyńska, A. Danczowska-Burdon, J. Sienkiewicz-Gromiuk, J. Therm. Anal. Calorim., 101, 671, (2010).
  • [37] R. Łyszczek, J. Anal. Appl. Pyrolysis, 86, 239, (2009).
  • [38] S. Siekierski, J. Inorg. Nucl. Chem., 43, 3381, (1981).
  • [39] J.C. Bailar, H.J. Emeleus, R. Nyholm, A.F. Trotman-Dickenson, Comprehensive inorganic chemistry (Pergamon Press Ltd., England, 1973)
  • [40] J.W. Kim, Y.D. Lee, H.G. Lee, ISIJ Int., 41, 116, (2001).
  • [41] M.D. Judd, B.A. Plunkett, M.I. Pope, J. Therm. Anal., 6, 555, (1974).
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_umcschem-2013-0013
JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.