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Number of results
2012 | 1 | 9-11

Article title

Selective Oxidation of Alcohols Catalyzed by a Hemicryptophane-Ruthenium Complex

Content

Title variants

Languages of publication

EN

Abstracts

EN
Hemicryptophane, a covalent molecular capsule that is composed of a cyclotriveratrylene (CTV) host unit, a tris(2-aminoethyl)amine (tren) ligand, and three rigid phenyl spacers, is a useful ligand for preparing synthetic transition metal complexes containing well-defined cavities that mimic the active sites of metalloenzymes. A method for the selective oxidation of primary alcohols using 5 mol % hemicryptophane-ruthenium(II) dichloride as the catalyst and cerium(IV) ammonium nitrate (CAN) as the terminal oxidant is described. The corresponding aldehydes of both benzylic and aliphatic alcohols are afforded in good to excellent yields under mild conditions without significant over-oxidation to produce the corresponding carboxylic acids.

Publisher

Year

Volume

1

Pages

9-11

Physical description

Dates

online
21 - 8 - 2012
accepted
25 - 7 - 2012
received
30 - 6 - 2012

Contributors

  • Department of Chemistry, Osaka Dental University, 8-1 Kuzuhahanazono-cho, Hirakata, Osaka 573-1121, Japan
  • Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan
  • Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan
author
  • Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan
  • Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan
  • Department of Chemistry, Osaka Dental University, 8-1 Kuzuhahanazono-cho, Hirakata, Osaka 573-1121, Japan
author
  • Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_supcat-2012-0002
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