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2014 | 2 | 1 |

Article title

Non-chromatographic methods focused on
speciation of arsenic and selenium in food and
environmental samples


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Speciation is a promising and essential tool in
the evaluation of the contamination of metals in food and
environmental samples. In this context, information about
the species of these elements is important considering that
toxic effects are directly related to their chemical forms. The
enormous progress in combining separation and detection
techniques has enabled the effective chemical speciation.
However, a possible source of error in studies of speciation
occurs during sample preparation. Appropriate treatment
of samples is necessary in order to ensure that interconversion
between the species does not occur during
the experimental procedure prior to the final analysis.
In this review, methods of sample preparation for the
determination of arsenic and selenium in food and
environmental samples are discussed. We decided to focus
on these elements since they account for around 50% of
all speciation studies. Procedures including conventional
extraction, microwave-assisted extraction and sonolysis
are discussed as simple ways to ensure species selectivity.
The main purpose of this review is to provide an update on
the recent literature concerning the strategies for arsenic
and selenium speciation and to critically discuss their
advantages and weaknesses compared with the commonly
accepted approach of combining non-chromatographic
and spectroscopic techniques. The problems focused on
involve sampling, sample preparation and storage, as well
as changes in ‘species information’ that occur during the
use of various separation technologies. These difficulties are described along with recent developments aimed at
overcoming these potential issues.







Physical description


14 - 1 - 2015
25 - 2 - 2014
3 - 10 - 2014


  • Institute of Chemistry,
    Federal University of Uberlândia, Av. João Naves de Ávila 2121, CEP
    38400-902, Uberlândia, MG, Brazil
  • Institute of Chemistry,
    Federal University of Uberlândia, Av. João Naves de Ávila 2121, CEP
    38400-902, Uberlândia, MG, Brazil
  • Department of Chemistry, Federal University of Goiás,
    Av. Dr. Lamartine Pinto de Avelar, 1120, CEP 75704-020, Catalão,
    GO, Brazil
  • Institute of Chemistry,
    Federal University of Uberlândia, Av. João Naves de Ávila 2121, CEP
    38400-902, Uberlândia, MG, Brazil
  • Institute of Chemistry,
    Federal University of Uberlândia, Av. João Naves de Ávila 2121, CEP
    38400-902, Uberlândia, MG, Brazil


  • [1] Olivas R., Donard O., Cámara C., Quevauviller P., Analyticaltechniques applied to the speciation of selenium inenvironmental matrices, Anal. Chim. Acta, 1994, 286, 357-370
  • [2] Templeton D., Ariese F., Cornelis R., Danielsson L., MuntauH., Leeuwen H., Lobinski R., Guidelines for terms related tochemical speciation and fractionation of elements. Definitions, structural aspects, and methodological approach. Pure Appl.Chem., 2000, 72, 1453-1470
  • [3] Alexander J., Benford D., Boobis A., Ceccatelli S., Cravedi J., DiDomenico A., Doerge D., Dogliotti E., Edler L., Farmer P., FilipičM., Fink-Gremmels J., Fürst P., Guerin T., Knutsen H., MachalaM., Mutti A., Schlatter J ., van Leeuwen R., Verger P., ScientificOpinion on Arsenic in Food. Eur. Food Safe Authority J., 2009, 7,1-199
  • [4] Hindmarsh J., McCurdy R., Clinical and environmental aspectsof arsenic toxicity, Crit. Rev. Clin. Lab. Sci., 1986, 23, 315-347[Crossref]
  • [5] Pizarro I., Gómez M., Cámara C., Palacios M.A., Arsenicspeciation in environmental and biological samples Extractionand stability studies, Anal. Chim. Acta, 2003, 495, 85–98
  • [6] Leermakers M., Baeyens W., De Gieter M., Smedts B., MeertC., De Bisschop H., Morabito R., Quevauviller. P., Toxic arseniccompounds in environmental samples: Speciation andvalidation, Trends Anal. Chem., 2006, 25, 1-10
  • [7] Barrachina A., Wu X., Gandolfo A., Norton G., Burló F., DeaconC., Meharg A., Inorganic arsenic contents in rice-based infantfoods from Spain, UK, China and USA, Environ. Pollut., 2012,163, 77-83
  • [8] ShemiraniaF., Baghdadia M., Ramezanib M., Preconcentrationand determination of ultra trace amounts of arsenic(III) andarsenic(V) in tap water and total arsenic in biological samplesby cloud point extraction and electrothermal atomic absorptionspectrometry, Talanta, 2005, 65, 882-887[Crossref]
  • [9] Katsoyiannis I., Zouboulis A., Application of biologicalprocesses for the removal of arsenic from groundwaters, WaterRes., 2004, 38, 17-26[Crossref]
  • [10] Pedrero Z., Madrid Y., Novel approaches for seleniumspeciation in foodstuffs and biological specimens: A review,Anal. Chim. Acta, 2009, 634, 135-152
  • [11] Mao X., Hu B., He M., Chen B., High polar organic–inorganichybrid coating stir bar sorptive extraction combined with highperformance liquid chromatography–inductively coupledplasma mass spectrometry for the speciation of seleno-aminoacids and seleno-oligopeptides in biological samples, J.Chromatogr., A, 2012, 1256, 32–39
  • [12] Najafi N., Seidi S., Alizadeh R., Tavakoli H., Inorganic seleniumspeciation in environmental samples using selective electrodepositioncoupled with electrothermal atomic absorptionspectrometry, Spectrochim. Acta, Part B, 2010, 65, 334-339[Crossref]
  • [13] Scott M., Morgan J., Reactions at oxide surfaces. 2. Oxidationof Se(IV) by synthetic birnessite. Environ. Sci. Techonol., 1996,30, 1990-1996[Crossref]
  • [14] Pinho J., Canario J, Cesario R., Vale C., A rapid digestion methodwith ICP–MS detection for the determination of selenium in drysediments, Anal. Chim. Acta, 2005, 551, 207-212
  • [15] Kawano T., Nishidea A., Okutsua K., Minamib H., Zhanga Q.,Inouea S., Atsuyaa I., Determination of selenium in biologicalsamples by slurry sampling-electrothermal vaporization-in situfusion-isotope dilution-microwave-induced nitrogen plasmamass spectrometry, Spectrochim. Acta Part B, 2005, 60,327-331[Crossref]
  • [16] Rotruck J., Pope A., Ganther H., Swanson A., Hafeman D.,Hoekstra W., Selenium: Biochemical role as a component ofglutathione peroxidase, Science, 1973, 179, 588-590
  • [17] Shrivas K., Patel D., Ultrasound assisted-hollow fibreliquid-phase microextraction for the determination of seleniumin vegetable and fruit samples by using GF-AAS, Food Chem.,2011, 124, 1673-1677
  • [18] Lippman S.M., Klein E.A., Goodman P.J. et al., Effect ofSelenium and Vitamin E on Risk of Prostate Cancer and OtherCancers, J. Am. Med. Assoc., 2009, 301, 39-51
  • [19] Barceloux D.G., Selenium, J. Toxicol. Clin.Toxicol., 1999, 37,145-172[Crossref]
  • [20] Beilstein M.A., Whanger P.D., Yang G.Q., Chemical forms ofselenium in corn and rice grown in a high selenium area ofChina. Biomed Environ Sci., 1991, 4, 392-398
  • [21]Vinceti M., Bonvicini F., Bergomi M., Malagoli C., Possibleinvolvement of overexposure to environmental selenium in theetiology of amyotrophic lateral sclerosis: a short review, Ann.Ist. Super. Sanità, 2010, 46, 279-283
  • [22] Michalke, B., Element speciation definitions, analyticalmethodology, and some examples, Ecotoxic. Environ. Saf.,2003, 56, 122–139[Crossref]
  • [23] Taylor A., Branch S., Halls D. J., Owen L. M. W., White M.,Atomic Spectrometry Update - Clinical and biological materials,food and beverages, J. Anal. At. Spectrom., 1998, 13, 57–106[Crossref]
  • [24] Vieira M., Grinberg P., Bobeda C., Reyes M. N. M., Campos R.C., Non-chromatographic atomic spectrometric methods inspeciation analysis: A review, Spectrochim. Acta, Part B, 2009,64, 459-476[Crossref]
  • [25] Ariza J. L. G., Morales E., Sanchez-Rodas D., Giraldez I.,Stability of chemical species in environmental matrices, TrendsAnal. Chem., 2000, 19, 200-209
  • [26] Versieck, J., Barbier, F., Cornelis, R., Hoste, J., Samplecontamination as a source of error in trace element analysis ofbiological samples, Talanta, 1982, 29, 972–978
  • [27] Dunemann, L., Begerow, J., Kopplungstechniken zur Elementspeziesanalytik.Wiley-VCH, Weinheim, 1995
  • [28] Batley, G.E., Physico-chemical separation methods for traceelement speciation in aquatic samples. In: Batley, G.E. (Ed.),Trace Element Speciation: Analytical Methods and Problems.CRC Press, Boca Raton, FL, 1989, 43–76
  • [29] Caroli S., Chemical speciation: a decade of progress. In: Caroli,S. (Ed.), Element Speciation in Bioinorganic Chemistry. Wiley,New York, 1996, 1–18
  • [30] Schramel, P., Hasse, S., Iodine determination in biologicalmaterial by ICP-MS. Mikrochim. Acta, 1994, 116, 205–209
  • [31] Chaem V., Agemian H., Preservation of inorganic arsenicspecies at microgram levels in water samples, Analyst, 1980,105, 737-743
  • [32] Hall G. E. M., Pelchat J. C., Gauthier G., Stability of inorganicarsenic (III) and arsenic (V) in water samples, J. Anal. At.Spectrom., 1999, 14, 205-213[Crossref]
  • [33] Lagarde F., Amran M. B., Leroy M. J. F., Demesmay C., Olle M.,Lamotte A., Muntau H., Michel P., Thomas P., Caroli S., LarsenE., Bonner P., Rauret G., Foulkes M., Howard A., Griepink B.,.Maier E. A, Improvement scheme for the determination ofarsenic species in mussel and fish tissues, Fresenius J. Anal.Chem., 1999, 363, 5-11
  • [34] Reineeke H., Dunemann L., Does the supplementation of metalions modify the intrinsic distribution of element species in foodextracts? Fresenius J. Anal. Chem., 1990, 338, 630 - 634
  • [35] Gonzalvez A., Cervera M.L., Armenta S., Guardia M., A reviewof non-chromatographic methods for speciation analysis, Anal.Chim. Acta, 2009, 636, 129–157
  • [36] González J., Lavilla I., Bendicho C., Evaluation of non-chromatographicapproaches for speciation of extractable As(III) andAs(V) in environmental solid samples by FI-HGAAS, Talanta,2003, 59, 525-534
  • [37] Dietz C., Sanz J., Sanz E., Muñoz-Olivas R., Cámara C., Currentperspectives in analyte extraction strategies for tin and arsenicspeciation, J. Chromatogr., A, 2007, 1153, 114-129
  • [38] Niegel C., Matysik F., Analytical methods for the determinationof arsenosugars – A review of recent trends and developments,Anal. Chim. Acta, 2010, 657, 83-99
  • [39] Rubio R., Ruiz-Chancho M., López-Sánchez J., Samplepre-treatment and extraction methods that are crucial toarsenic speciation in algae and aquatic plants, Trends Anal.Chem., 2010, 29, 53-69
  • [40] Drahota P., Rohovec J., Filippi M., Mihaljevič M., Rychlovský P.,Červený V., Pertold Z., Mineralogical and geochemical controlsof arsenic speciation and mobility under different redoxconditions in soil, sediment and water at the Mokrsko-Westgold deposit, Czech Republic, Sci. Total Environ., 2009, 407,3372-3384
  • [41] Aggett J., Aspell A., The determination of As(III) and totalarsenic by atomic-absorption spectroscopy, Analyst(Cambridge, U. K.), 1976; 101, 341-347[Crossref]
  • [42] Yasui A., Tsutsumi C., Toda S., Selective determination ofinorganic arsenic(III), (V) and organic arsenic in biologicalmaterials by solvent extraction-Atomic absorption spectrophotometry,Agric. Biol. Chem., 1978, 42, 2139-2145[Crossref]
  • [43] Münz H., Lorenzen W., Differenzierte Bestimmung von anorganischemund organischem Arsen in Lebensmitteln mit Hilfe derAtomabsorptions-Spektroskopie, Fresenius Z. Anal. Chem.,1984, 319, 395-398
  • [44] Ghasemi E., Najafi N., Raofie F., Ghassempour A., Simultaneousspeciation and preconcentration of ultra-traces of inorganictellurium and selenium in environmental samples by hollowfiber liquid phase microextraction prior to electrothermalatomic absorption spectroscopy determination, J. Hazard.Mater., 2010, 181, 491-496
  • [45] Ficklin W., Extraction and speciation of arsenic in lacustrinesediments, Talanta, 1990, 37, 831-834[Crossref]
  • [46] Giacomino A., Malandrino M., Abollino O., Velayutham M.,Chinnathangavel T., Mentasti E., An approach for arsenic in acontaminated soil: Speciation, fractionation, extraction andeffluent decontamination, Environ. Pollut., 2010, 158, 416-423[Crossref]
  • [47] Geng W., Komine R., Ohta T., Nakajima T., Takanashi H., OhkiA., Arsenic speciation in marine product samples: Comparisonof extraction–HPLC method and digestion–cryogenic trapmethod, Talanta, 2009, 79, 369-375[Crossref]
  • [48] Gómez-Ariza J., Morales E., Giráldez I., Sánchez-Rodas D.,Velasco A., Sample treatment in chromatography-basedspeciation of organometallic pollutants, J. Chromatogr., A,2001, 938, 211–224
  • [49] Martens D., Suarez D., Selenium speciation of soil/sedimentdetermined with sequential extractions and hydride generationatomic absorption spectrometry, Environ. Sci. Technol., 1997,31, 133-139[Crossref]
  • [50] Méndez H., Lavilla I., Bendicho C., Mild sample pretreatmentprocedures based on photolysis and sonolysis-promotedredox reactions as a new approach for determination of Se(IV),Se(VI) and Se(–II) in model solutions by the hydride generationtechnique with atomic absorption and fluorescence detection,J. Anal. At. Spectrom., 2004, 19, 1379-1385
  • [51] Li S., Deng N., Separation and preconcentration of Se(IV)/Se(VI) species by selective adsorption onto nanometer-sizedtitanium dioxide and determination by graphite furnace atomicabsorption spectrometry, Anal. Bioanal. Chem., 2002, 374,1341-1345
  • [52] Manning B., Martens D., Speciation of arsenic(III) andarsenic(V) in sediment extracts by high-performance liquidchromatography−hydride generation atomic absorptionspectrophotometry, Environ. Sci. Technol., 1997, 31, 171–177[Crossref]
  • [53] Wang S., Liang D., Wang D., Wei W., Fu D., Lin Z., Seleniumfractionation and speciation in agriculture soils andaccumulation in corn (Zea mays L.) under field conditions inShaanxi Province, China. Sci. Total Environ., 2012, 427-428
  • [54] Serafimovski I., Karadjova I.B., Stafilov T., Tsalev D.L.,Determination of total arsenic and toxicologically relevantarsenic species in fish by using electrothermal and hydridegeneration atomic absorption spectrometry, Microchem. J.,2006, 83, 55-60[Crossref]
  • [55] Ubonnuch C., Ruangwises S., Gritsanapan W., Ruangwises N.,Total and Inorganic Arsenic Contents in Some Edible ZingiberaceousRhizomes in Thailand, Evid. Based Complement.Alternat. Med., Published online 2013 April
  • [56] Gawloska-Kamocka A., Lodzi W.S.Z., Speciation analysis ofinorganic forms of selenium in confectionery products, J.Elementol., 2007, 12, 105-110
  • [57] Nóbrega J., Trevisan L., Araújo G., Nogueira A., Focusedmicrowave-assisted strategies for sample preparation,Spectrochim. Acta Part B, 2002, 57, 1855-1876[Crossref]
  • [58] Schmitt V., de Diego A., Cosnier A., Tseng C., Moreau J., DonardO., Open focused microwave-assisted sample preparationprocedures: fundamentals and application to the speciation oftin and mercury in environmental samples, Spectroscopy, 1997,13, 99-111
  • [59] Guardia M., Garrigues S., Handbook of Green AnalyticalChemistry, Energy Savings in Analytical Chemistry, John Wiley &Sons, Inc., United Kington, 2012
  • [60] Jain T., Jain V., Pandey R., Vyas A., Shukla S., Microwaveassisted extraction for phytoconstituents - An overview, Asian J.Res. Chem., 2009, 2, 19-25
  • [61] Luque-García J., de Castro M., Where is microwave-basedanalytical equipment for solid sample pre-treatment going?Trends Anal. Chem., 2003, 22, 90-98
  • [62] Costa L., Santos D., Hatje V., Nóbrega J., Korn M., Focusedmicrowave-assisted acid digestion: Evaluation of losses ofvolatile elements in marine invertebrate samples, J. FoodCompos. Anal., 2009, 22, 238-241[Crossref]
  • [63] Huie C., A review of modern sample-preparation techniques forthe extraction and analysis of medicinal plants, Anal. Bioanal.Chem., 2002, 373, 23-30
  • [64] Dunemann L., Meinerling M., Comparison of differentmicrowave-based digestion techniques in view of theirapplication to fat-rich foods, Fresenius J. Anal. Chem., 1992,342, 714-718
  • [65] Al-Harahsheh M., Kingman S., Microwave-assisted leaching - Areview, Hydrometallurgy, 2004, 73, 189-203
  • [66] Chen L., Song D., Tian Y., Ding L., Yu A., Zhang H., Applicationof on-line microwave sample-preparation techniques, TrendsAnal. Chem., 2008, 27, 151-159
  • [67] Burguera J., Carrero P., Burguera M., Rondon C., BrunettoM., Gallignani M., Flow injection for the determination ofSe(IV) and Se(VI) by hydride generation atomic absorptionspectrometry with microwave oven on-line prereduction ofSe(VI) to Se(IV), Spectrochim. Acta Part B, 1996, 51, 1837-1847[Crossref]
  • [68] Gallignani M., Valero M., Brunetto M., Burguera J., BurgueraM., de Peña Y., Sequential determination of Se(IV) and Se(VI)by flow injection-hydride generation-atomic absorptionspectrometry with HCl:HBr microwave aided pre-reduction ofSe(VI) to Se(IV), Talanta, 2000, 52, 1015-1024[Crossref]
  • [69] LaFuenteJ., Sánchez M., Marchante-gayón J., Uria J.,Sanz-Medel A., On-line focused microwave digestionhydridegeneration of inorganic and organic selenium: Totaldetermination and inorganic selenium speciation by atomicabsorption spectrometry, Spectrochim. Acta, Part B, 1996, 51,1849-1857[Crossref]
  • [70] Tuzen M., SaygiK., Soylak M., Separation and speciation ofselenium in food and water samples by the combination ofmagnesium hydroxide coprecipitation-graphite furnace atomicabsorption spectrometric determination, Talanta, 2007, 71,424-429[Crossref]
  • [71] Gong Z., Lu X., Ma M., Watt C., Le X., Arsenic speciationanalysis, Talanta, 2002, 58, 77-96
  • [72] Barra C., Santelli R. Abraão J., Guardia M., Arsenic speciation –A review, Quím. Nova, 2000, 23, 58-70[Crossref]
  • [73] Ringmann S., Boch K., Marquardt W., Schuster M., SchlemmerG., Kainrath P., Microwave-assisted digestion of organoarseniccompounds for the determination of total arsenic in aqueous,biological, and sediment samples using flow injection hydridegeneration electrothermal atomic absorption spectrometry,Anal. Chim. Acta, 2002, 452, 207-215
  • [74] Lamble K., Hill S., Microwave digestion procedures forenvironmental Matrices. Critical Review, Analyst, 1998, 123,103-133[Crossref]
  • [75] Tuzen M., Saygi K., Karaman I., Soylak M., Selective speciationand determination of inorganic arsenic in water, food andbiological samples, Food Chem. Toxicol., 2010, 48, 41-46[Crossref]
  • [76] Pasias I., Thomaidis N., Piperaki E., Determination of totalarsenic, total inorganic arsenic and inorganic arsenic speciesin rice and rice flour by electrothermal atomic absorptionspectrometry, Microchem. J., 2013, 108, 1-6
  • [77] Golimowski J., Golimowska K., UV-photooxidation aspretreatment step in inorganic analysis of environmentalsamples, Anal. Chim. Acta, 1996, 325, 111-133
  • [78] USEPA, “Chapter 8: Ultraviolet Radiation”, Alternativedisinfectants and Oxidants Guidance Manual, EPA815-R-99014, April 1999: www.epa.gov/safewater/mdbp/pdf/after/chapt_8.pdf/Accessed January 2013
  • [79] Bendicho C., Pena F., Costas M., Gil S., Lavilla I.,Photochemistry-based sample treatments as greenerapproaches for trace-element analysis and speciation, TrendsAnal. Chem., 2010, 29, 681-691
  • [80] Capelo-Martinéz J., Ximénez-Embún P., Madrid Y., Cámara C.,Advanced oxidation processes for sample treatment in atomicspectrometry, Trends Anal. Chem., 2004, 23, 331-340
  • [81] Florian D., Knapp G., High-temperature, microwave-assisted UVdigestion: a promising sample preparation technique for traceelement analysis, Anal. Chem., 2001, 73, 1515-1520[Crossref]
  • [82] Brandão G., Aureliano M., Sauthier M., dos Santos W.,Photo-oxidation using UV radiation as a sample preparation procedure for the determination of copper in fruit juices byflame atomic absorption spectrometry, Anal. Methods, 2012, 4,855-858[Crossref]
  • [83] Chen Y., Zhou M., Tong J., Belzile N., Application ofphotochemical reactions of Se in natural waters by hydridegeneration atomic fluorescence spectrometry, Anal. Chim. Acta,2005, 545, 142-148
  • [84] Chen Y., Zhou X., Tong J., Truong Y., Belzile N., Photochemicalbehavior of inorganic and organic selenium compounds invarious aqueous solutions, Anal. Chim. Acta, 2005, 545,149-157
  • [85] Cabon J., Cabon N., Determination of arsenic species inseawater by flow injection hydride generation in situ collectionfollowed by graphite furnace atomic absorption spectrometrystability of As(III), Anal. Chim. Acta, 2000, 418, 19-31
  • [86] Castro E., Lavilla I., Bendicho C., Photolytic oxidation of Asspecies for determination of total As (including the ‘hidden’As fraction) in coastal seawater by hydride generation-atomicfluorescence spectrometry, Talanta, 2007, 71, 51-55[Crossref]
  • [87] Priego-Capote F., Castro M., Ultrasound-assisted digestion: Auseful alternative in sample preparation, J. Biochem. Biophys.Methods, 2007, 70, 299-310[Crossref]
  • [88] Güngör H., Elik A., Comparison of ultrasound-assisted leachingwith conventional and acid bomb digestion for determinationof metals in sediment samples, Microchem. J., 2007, 86, 65-70[Crossref]
  • [89] Calle I., Cabaleiro N., Lavilla I., Bendicho C., Analyticalevaluation of a cup-horn sonoreactor used for ultrasoundassistedextraction of trace metals from troublesome matrices,Spectrochim. Acta, Part B, 2009, 64, 874-883[Crossref]
  • [90] Ashley K., Andrews R., Cavazos L., Demange M., Ultrasonicextraction as a sample preparation technique for elementalanalysis by atomic spectrometry, J. Anal. At. Spectrom., 2001,16, 1147-1153[Crossref]
  • [91] Cava-Montesinos P., Guardia A., Teutsch C., Cervera M.,Guardia M., Non-chromatographic speciation analysis ofarsenic and antimony in milk hydride generation atomicfluorescence spectrometry, Anal. Chim. Acta, 2003, 493,195-203
  • [92] Cava-Montesinos P., Nilles K., Cervera M., Guardia M.,Non-chromatographic speciation of toxic arsenic in fish,Talanta, 2005, 66, 895-901
  • [93] Reyes M., Cervera M., Campos R., Guardia M., Determinationof arsenite, arsenate, monomethylarsonic acid anddimethylarsinic acid in cereals by hydride generation atomicfluorescence spectrometry, Spectrochim. Acta, Part B, 2007,62, 1078-1082[Crossref]
  • [94] Reyes M., Cervera M., Campos R., Guardia M. Non-chromatographicspeciation of toxic arsenic in vegetables by hydridegeneration-atomic fluorescence spectrometry after ultrasoundassistedextraction, Talanta, 2008, 75, 811-816[Crossref]
  • [95] Gonzálvez A., Llorens A., Cervera M., Armenta S., GuardiaM., Non-chromatographic speciation of inorganic arsenicin mushrooms by hydride generation atomic fluorescencespectrometry, Food Chem., 2009, 115, 360-364
  • [96] Zhao R., Zhao M., Wang H., Taneike Y., Zhang X., Arsenicspeciation in moso bamboo shoot - A terrestrial plant thatcontains organoarsenic species, Sci. Total Environ., 2006, 371,293-303
  • [97] Reyes M., Cervera M., Guardia M., Determination of total Sb,Se, Te, and Bi and evaluation of their inorganic species in garlic by hydride-generation–atomic-fluorescence spectrometry,Anal. Bioanal. Chem., 2009, 394, 1557-1562
  • [98] Martinis E., Escudero L., Berton P., Monasterio R., Filippini M.,Wuilloud R., Determination of inorganic selenium species inwater and garlic samples with on-line ionic liquid dispersivemicroextraction and electrothermal atomic absorptionspectrometry, Talanta, 2011, 85, 2182-2188[Crossref]
  • [99] Tokman N., The use of slurry sampling for the determination ofmanganese and copper in various samples by electrothermalatomic absorption spectrometry, J. Hazard. Mater., 2007, 143,87-94
  • [100] Macedo S., Jesus R., Garcia K., Hatje V., Queiroz A., FerreiraS., Determination of total arsenic and arsenic (III) in phosphatefertilizers and phosphate rocks by HG-AAS after multivariateoptimization based on Box-Behnken design, Talanta, 2009, 80,974-979[Crossref]
  • [101] Hatje V., Macedo S., Jesus R., Cotrim G., Garcia K., QueirozA., Ferreira S., Inorganic As speciation and bioavailability inestuarine sediments of Todos os Santos Bay, BA, Brazil, Mar.Pollut. Bull., 2010, 60, 2225-2232[Crossref]
  • [102] Macedo S., Santos D., Jesus R., Rocha G., Ferreira S., AndradeJ., Development of an analytical approach for determination oftotal arsenic and arsenic (III) in airborne particulate matter byslurry sampling and HG-FAAS, Microchem. J., 2010, 96, 46-49[Crossref]
  • [103] López-García I., Briceño M., Hernández-Córdoba M.,Non-chromatographic screening procedure for arsenicspeciation analysis in fish-based baby foods by using electrothermalatomic absorption spectrometry, Anal. Chim. Acta,2011, 699, 11-17

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