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2013 | 1 | 10-17
Article title

Application of poly (N-phenylethanolamine) modified
MWCNTs as a new sorbent for solid-phase extraction of
trace palladium ions in soil and water samples

Content
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EN
Abstracts
EN
This paper describes, a new, sensitive, and low cost solid-phase extraction
(SPE) method using a poly(N-phenylethanolamine) /multi-walled carbon
nanotubes (MWCNTs) nanocomposite for extraction, pre-concentration,
and flame atomic absorption spectrometric (FAAS) determination of trace
level palladium in distilled water, tap water, Caspian sea water, Persian
Gulf water, spring water, lake water and soil samples, as well as real
samples. The poly(N-phenylethanolamine)/MWCNTs nanocomposite
were characterized using Fourier Transform-infrared (FT-IR) spectroscopy,
thermo-gravimetric analysis (TGA) and scanning electron microscopy
(SEM). Factors affecting the pre-concentration of palladium, including
sample pH, flow rate, and type and volume of eluent, were investigated.
The effect of interfering ions and break through volume on the separation
and determination of palladium ions was also determined. The maximum
sorbent capacity of the poly (N-phenylethanolamine)/MWCNTs
nanocomposite was calculated to be 101.5 mg g−1. The pre-concentration
factor, relative standard deviation, and limit of detection of the method
were found to be 150, 2.8% (n=10), and 0.09 ng mL−1, respectively. The
presented method was compared to certified reference materials, and
finally, the presented technique was applied to different matrices spiked
with 5 ng mL−1 of analyte.
Publisher

Year
Volume
1
Pages
10-17
Physical description
Dates
online
10 - 06 - 2013
accepted
16 - 03 - 2013
received
16 - 11 - 2012
Contributors
  • Department of Chemistry,
    Shahid Beheshti University, G.C,
    1983963113, Tehran, Iran
author
  • Department of Chemistry,
    Shahid Beheshti University, G.C,
    1983963113, Tehran, Iran, me-bagheri@sbu.ac.ir
author
  • Department of Chemistry,
    Islamic Azad University,
    Central Tehran Branch, Tehran, Iran
  • Department of Chemistry,
    Shahid Beheshti University, G.C,
    1983963113, Tehran, Iran, m-nabid@sbu.ac.ir
author
  • Department of Chemistry,
    Shahid Beheshti University, G.C,
    1983963113, Tehran, Iran
  • Department of Chemistry,
    School of Science, Azzahra University,
    Vanak, Tehran, Iran
  • Department of Chemistry,
    School of Science, Azzahra University,
    Vanak, Tehran, Iran
  • Department of Chemistry,
    School of Science, Azzahra University,
    Vanak, Tehran, Iran
References
  • [1] Zereini, F.; Alt, F. Palladium Emission in the Environment,Springer-Verlag: Berlin. Heidelberg, 2006.
  • [2] Edmiston, C.; Goheen, M.P.; Seabrook, G.R.; JohnsonCh.; Lewis B.; Brown K.R.; Towne, J.B. Impact of selectiveantimicrobial agents on staphylococcal adherence tobiomedical devices. Am. J. Surg., 2006, 192, 344-354.
  • [3] Zhu, Y.; Khan, Z.; Masel, R.I. The behavior of palladiumcatalysts in direct formic acid fuel cells. J. Power Sources,2005, 139, 15-20.
  • [4] Hooda, P.S.; Miller, A.; Edwards, A.C. The distribution ofautomobile catalysts cast platinum, palladium and rhodiumin soils adjacent to roads and their uptake by grass. Sci. TotalEnviron., 2007, 374, 384-392.[WoS]
  • [5] Sures, B.; Zimmermann, S. Impact of humic substanceson the aqueous solubility, uptake and bioaccumulation ofplatinum, palladium and rhodium in exposure studies withDreissenapolymorpha. Environ. Pollut., 2007, 146, 444-451.[WoS]
  • [6] Shemirani, F.; RahnamaKozani, R.; Jamali, M.R.; Assadi, Y.;MilaniHosseini, M.R. Cloud point extraction, preconcentration,and spectrophotometric determination of palladium in watersamples. Int. J. Environ. Anal. Chem., 2006, 86, 1105-1112.
  • [7] Wataha, J.C.; Hanks, C.T. Biological effects of palladiumand risk of using palladium in dental casting alloys. J. Oral.Rehabil, 1996, 23, 309-320.
  • [8] Tokalioglul, S.; Yılmaz, V.; Kartal, S.; Delibas, A.; Soykan, C. Solidphase extraction of Pd(II) on a newly synthesized chelating resinprior to determination by flame atomic absorption spectrometry.Microchim. Acta, 2009, 165, 347-352.
  • [9] Jamali, M.R.; Assadi, Y.; Shemirani, F.; Salavati-Niasari,M. Application of thiophene-2- carbaldehyde-modifiedmesoporous silica as a new sorbent for separation andpreconcentration of palladium prior to inductively coupledplasma atomic emission spectrometric determination.Talanta, 2007, 71, 1524-1529.
  • [10] Mohamadi, M.; Mostafavi, A. A novel solidified floatingorganic drop microextraction based on ultrasound-dispersionfor separation and preconcentration of palladium in aqueoussamples. Talanta, 2010, 81, 309-313.[WoS]
  • [11] Soylak, M.; Tuzen, M. Coprecipitation of gold(III), palladium(II)and lead(II) for their flame atomic absorption spectrometricdeterminations. J. Hazard. Mater., 2008, 152, 656-661.[WoS]
  • [12] Oguri, K.; Shimoda, G.; Tatsumi, Y. Quantitativedetermination of gold and the platinum group elementsin geological samples using improved NiS fire-assay andtellurium coprecipitation with inductively coupled plasmamassspectrometry (ICPMS). Chem. Geol, 1999, 157, 189-197.
  • [13] Pearson, D.G.; Woodland, S.J. Solvent extraction/anionexchange separation and determination of PGEs (Os, Ir,Pt, Pd, Ru) and Re–Os isotopes in geological samples byisotope dilution ICP-MS. Chem. Geol, 2000, 165, 87-107.
  • [14] Igarashi, Sh.; Ide, N.; Takagai, Y. High-performance liquidchromatographic– spectrophotometric determinationof copper(II) and palladium(II) with 5,10,15,20-tetrakis(4Npyridyl) porphine following homogeneous liquid–liquidextraction in the water– acetic acid– chloroform ternarysolvent system. Anal. Chim. Acta, 2000, 424, 263-269.
  • [15] Bagheri, A.; Behbahani, M.; Amini, M.M.; Sadeghi, O.;Taghizade, M.; Baghayi, L.; Salarian, M. Simultaneousseparation and determination of trace amounts of Cd(II) andCu(II) in environmental samples using novel diphenylcarbazidemodified nanoporous silica. Talanta, 2012, 89, 455-461.
  • [16] Behbahani, M.; Salarian, M.; Amini, M.M.; Sadeghi, O.;Bagheri, A.; Bagheri, S. Application of a New FunctionalizedNanoporous Silica for Simultaneous Trace Separation andDetermination of Cd(II), Cu(II), Ni(II), and Pb(II) in Food andAgricultural Products. Food Anal. Methods. DOI 10.1007/s12161-012-9545-9.[Crossref]
  • [17] Bagheri, A.; Behbahani, M.; Amini, M.M.; Sadeghi, O.;Tootoonchi, A.; Dahaghin, Z. Preconcentration and separationof ultra-trace palladium ion using pyridine-functionalizedmagnetic nanoparticles, Microchim. Acta., 2012, 178, 261–268.
  • [18] Bagheri, A.; Taghizadeh, M.; Behbahani, M.; Asgharinezhad,A.A.; Salarian, M.; Dehghani, A.; Ebrahimzadeh, H.;Amini, M.M. Synthesis and characterization of magneticmetal-organic framework (MOF) as a novel sorbent, andits optimization by experimental design methodology fordetermination of palladium in environmental samples.Talanta, 2012, 99, 132–139.
  • [19] Huck, C.W.; Bonn G.K. Recent developments in polymerbasedsorbents for solid-phase extraction, J. Chromatogr. A,2000, 885, 51-72.
  • [20] Ravelo-Pérez, L.M.; Herrera-Herrera, A.V.; Hernández-Borges, J.; Rodríguez-Delgado M.Á., Carbon nanotubes:Solid-phase extraction, J. Chromatogr. A, 2010, 1217, 2618-2641.
  • [21] Latorre, C.H.; Méndez, J.Á.; García, J.B.; Martín, S.G.; PeñaCrecente, R.M.; Carbon nanotubes as solid-phase extractionsorbents prior to atomic spectrometric determination ofmetal species: A review, Anal. Chim. Acta, 2012, 16-35.[Crossref]
  • [22] Ebrahimzadeh, H.; Behbahani, M.; Yamini, Y.; Adlnasab,L.; Asgharinezhad, A.A.Optimization of Cu(II)-ion imprintednanoparticles for trace monitoring of copper in water and fishsamples using a Box–Behnken design. Reactive & FunctionalPolymers, 2013, 73, 23–29.[WoS]
  • [23] Behbahani, M.; Taghizadeh, M.; Bagheri, A.; Hosseini, H.;Salarian, M.; Tootoonchi, A. A nanostructured ion-imprintedpolymer for the selective extraction and preconcentration ofultra-trace quantities of nickel ions. Microchim. Acta, 2012,178, 429–437.[WoS]
  • [24] Pyrzynska, K. Recent developments in the determination ofgold by atomic spectrometry techniques. Spectrochim. Acta.B, 2005, 60, 1316-1322.
  • [25] Li, X.; Wang, Y.; Yang, X.; Chen, J.; Fu, H.; Cheng, T.Conducting polymers in environmental analysis, TrAC TrendsAnal. Chem., 2012, 39, 163-179.
  • [26] Nabid, M.R.; Sedghi, R.; Bagheri,A.; Behbahani, M.;Taghizadeh, M.; AbdiOskooie, H.; Heravi, M.M. Preparation and application of poly(2-amino thiophenol)/MWCNTsnanocomposite for adsorption and separation of cadmiumand lead ions via solid phase extraction, J. Hazard. Mater.,2012, 203, 93-100.
  • [27] Nabid, M.R.; Sedghi, R.; Jamaat, P.R.; Safari, N.; Entezami,A.A. Catalytic oxidative polymerization of aniline by usingtransition-metal tetrasulfonatedphthalocyanine. AppliedCatalysis A, 2007, 328, 52-57.[WoS]
  • [28] Praveen, R.S.; Daniel, S.; Rao, T.P.; Sampath, S.; Rao, K.S.Flow injection on-line solid phase extractive preconcentrationof palladium(II) in dust and rock samples using exfoliatedgraphite packed microcolumns and determination by flameatomic absorption spectrometry. Talanta, 2006, 70 (2), 437-443.[Crossref]
  • [29] Ghaedi, M.; Shokrollahi, A.; Niknam, K.; Niknam, E.; Nijibi,A.; Soylak M. Cloud point extraction and flame atomicabsorption spectrometric determination of cadmium(II),lead(II), palladium(II) and silver(I) in environmental samples. J.Hazard. Mater., 2009, 168, 1022-1027.
  • [30] Venkatesh, G.; Singh, A.K. Enrichment and flame atomicabsorption spectrometric determination of palladium usingchelating matrices designed by functionalizing AmberliteXAD-2/16 and silica gel. Microchim. Acta, 2007, 159, 149-155.
  • [31] Jamali, M.R.; Assadi, Y.; Shemirani, F.; Salavati-Niasari,M. Application of thiophene-2- carbaldehyde-modifiedmesoporous silica as a new sorbent for separation andpreconcentration of palladium prior to inductively coupledplasma atomic emission spectrometric determination.Talanta, 2007, 71, 1524-1529.
  • [32] Di, P.; Davey, D.E. An optimized on-line preconcentrationsystem for analysis of trace gold in ore samples. Talanta,1995, 42, 1081-1088.
  • [33] Daniel, S.; Gladis, J. M.; PrasadaRao, T. Synthesis ofimprinted polymer material with palladium ion nanopores andits analytical application. Anal. Chim. Acta, 2003, 488, 173-182.
  • [34] Daniel, S.; Rao, P.P.; Rao, T.P. Investigation of differentpolymerization methods on the analytical performance ofpalladium(II) ion imprinted polymer materials. Anal. Chim.Acta, 2005, 536, 197-206.
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_sampre-2013-0002
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