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A high-resolution VUV laser absorption spectroscopy is used to investigate the photon-induced ion-pair formation in D2 in the spectral region from 140117.4 to 140732.0 cm−1. We report determination of photoionization efficiency in ortho-para D2 in supersonic molecular beam with energy resolution of 0.1 cm−1. The assignment of the superexcited D2 Rydberg states is done based on the quantum defect theory.
Department of Physics and Key Laboratory of Atomic and Molecular Nanosciences of Chinese Education Ministry, Tsinghua University, 100084, Beijing, China
Department of Physics and Key Laboratory of Atomic and Molecular Nanosciences of Chinese Education Ministry, Tsinghua University, 100084, Beijing, China