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Abstracts
In this work the etherification reaction of glycerol with isobutene (IB) and tert-butyl alcohol (TBA) has been studied with the aim of preparing mixtures with high content of poly-substituted ethers. The results obtained using solid acid catalysts have shown that the reaction with IB proceeds at a high rate but the formation of undesired di-isobutene (DIB) represents a serious problem when catalysts with high density of acid sites, such as Amberlyst, are used. When using TBA as a reactant, the main problem is the formation of water that, due to thermodynamic reasons, prevents the formation of poly-substituted ethers regardless of the catalyst used. Some preliminary experiments carried out with a water permselective tubular membrane have demonstrated that the yield of poly-substituted ethers significantly increases once water was selectively removed from the reaction medium by recirculation of the gas phase.
Journal
Year
Volume
Issue
Pages
1248-1254
Physical description
Dates
published
1 - 12 - 2014
online
7 - 6 - 2014
Contributors
author
- “Nicola Giordano”
author
- “Nicola Giordano”
author
- University of Messina
author
- “Nicola Giordano”, francesco.frusteri@itae.cnr.it
References
- [1] N. Rahmat, A.Z. Abdullah, A.R. Mohamed, Renew. Sust. Energ. Rev. 14, 987 (2010) http://dx.doi.org/10.1016/j.rser.2009.11.010[Crossref]
- [2] C. Cannilla, G. Bonura, F. Arena, E. Rombi, F. Frusteri, Catal. Today 195(1), 32 (2012) http://dx.doi.org/10.1016/j.cattod.2012.04.051[Crossref]
- [3] Y. Zheng, X. Chen, Y. Shen, Chem. Rev. 108, 5253 (2008) http://dx.doi.org/10.1021/cr068216s[Crossref]
- [4] D.M. Alonso, S.G. Wettstein, J. Sumesic, Chem. Soc. Rev. 41, 8075 (2012) http://dx.doi.org/10.1039/c2cs35188a[Crossref]
- [5] H. Noureddini, US Patent 6,174,501 (2001)
- [6] V.P. Gupta, US Patent 5,476,971 (1995)
- [7] D.S. Bradin, US Patent 5,578,090 (1996)
- [8] T.J. Jalisnki, US Patent WO2006084048-A1 (2006)
- [9] P.J. Delgado, EP Patent 1,331,260 A2 (2003)
- [10] F. Frusteri, C. Cannilla, G. Bonura, L. Spadaro, A. Mezzapica, C. Beatrice, G. Di Blasio, C. Guido, Top. Catal. 56(1–8), 378 (2013) http://dx.doi.org/10.1007/s11244-013-9983-7[Crossref]
- [11] E. Lotero, J.G. Goodwin Jr, D.A. Bruce, K. Suwannakarn, Y. Liu, D.E. Lopez, Catal. 19, 41 (2006)
- [12] F. Ataya, M.A. Dube, M. Ternan, Energy Fuels 22, 679 (2008) http://dx.doi.org/10.1021/ef7005386[Crossref]
- [13] R. Palkovits, I. Nieddu, C.A. Kruithof, R.J.M. Klein Gebbink, B.M. Wecknuysen, Chem. Eur. J. 14, 8995 (2008) http://dx.doi.org/10.1002/chem.200800792[Crossref]
- [14] J.A. Melero, G. Vicente, G. Morales, M. Paniagua, J. M. Moreno, R. Roldán, A. Ezquerro, C. Pérez, Appl. Catal. A-Gen. 346, 44 (2008) http://dx.doi.org/10.1016/j.apcata.2008.04.041[Crossref]
- [15] C. Beatrice, G. Di Blasio, M. Lazzaro, C. Cannilla, G. Bonura, F. Frusteri, F. Asdrubali, G. Baldinelli, A. Presciutti, F. Fantozzi, G. Bidini, P. Bartocci, Appl. Energ. 102, 63 (2013) http://dx.doi.org/10.1016/j.apenergy.2012.08.006[Crossref]
- [16] M.O. Guerrero-Pérez, J.M Rosas, J. Bedi, J. Rodríguez-Mirasol, R. Cordero, Recent Patents on Chemical Engineering 2, 11 (2009) http://dx.doi.org/10.2174/2211334710902010011[Crossref]
- [17] F. Frusteri, L. Frusteri, C. Cannilla, G. Bonura, Bioresour. Technol. 118, 350 (2012) http://dx.doi.org/10.1016/j.biortech.2012.04.103[Crossref]
- [18] H.J. Lee, D. Seung, K.S. Jung, H. Kim, I.N. Filimonov, Appl. Catal. A-Gen. 390, 235 (2010) http://dx.doi.org/10.1016/j.apcata.2010.10.014[Crossref]
- [19] R.S. Karinen, A.O.I. Krause, Appl. Catal. A-Gen. 306, 128 (2006) http://dx.doi.org/10.1016/j.apcata.2006.03.047[Crossref]
- [20] K. Klepáčová, D. Mravec, M. Bajus, Appl. Catal. A-Gen. 294, 141 (2005) http://dx.doi.org/10.1016/j.apcata.2005.06.027[Crossref]
- [21] K. Klepáčová, D. Mravec, A. Kaszonyi, M. Bajus, Appl. Catal. A-Gen. 328, 1 (2007) http://dx.doi.org/10.1016/j.apcata.2007.03.031[Crossref]
- [22] W. Zhao, C. Yi, B. Yang, J. Hu, Xinming Huang, Fuel Process Technol. 112, 70 (2013) http://dx.doi.org/10.1016/j.fuproc.2013.02.012[Crossref]
- [23] M.D. González, P. Salagre, E. Taboada, J. Llorca, E. Molins, Appl. Catal. B-Env. 136–137, 287 (2013) http://dx.doi.org/10.1016/j.apcatb.2013.02.018[Crossref]
- [24] F. Frusteri, F. Arena, G. Bonura, C. Cannilla, L. Spadaro, O. Di Blasi, Appl. Catal. A-Gen. 367, 77 (2009) http://dx.doi.org/10.1016/j.apcata.2009.07.037[Crossref]
- [25] K. Klepáčová, D. Mravec, M. Bajus, Chem. Pap. 60(3), 224 (2006) http://dx.doi.org/10.2478/s11696-006-0040-x[Crossref]
- [26] K. Klepáčová, D. Mravec, E. Hájeková, M. Bajus, Petrol. Coal, 45(1-2) 54 (2003)
- [27] R. Luque, V. Buadrin, J.H. Clark, D. J. Macquarrie, App. Catal. B-Env. 82, 157 (2008) http://dx.doi.org/10.1016/j.apcatb.2008.01.015[Crossref]
- [28] J. Janaun, N. Ellis, J. Appl. Sci, 10(21), 2633 (2010) http://dx.doi.org/10.3923/jas.2010.2633.2637[Crossref]
- [29] W. Kiatkittipong, P. Intaracharoen, N. Laosiripojana, C. Chaisuk, P. Praserthdam, S. Assabumrungrat, Comput. Chem. Eng. 35, 2034 (2011) http://dx.doi.org/10.1016/j.compchemeng.2011.01.016[Crossref]
- [30] M.L. Honkela, A.O.I. Krause, Ind. Eng. Chem. Res. 43, 3251 (2004) http://dx.doi.org/10.1021/ie030842h[Crossref]
- [31] M.L. Holkela, A. Root, M. Lindblad, A.O.I. Krause, Appl. Catal. A-Gen. 295, 216 (2005) http://dx.doi.org/10.1016/j.apcata.2005.08.023[Crossref]
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-014-0546-y