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Journal
2014 | 12 | 9 | 937-952
Article title

A multi-property fluorescent probe for the investigation of polymer dynamics near the glass transition

Content
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EN
Abstracts
EN
In addition to the commonly observed single molecule fluorescence intensity fluctuations due to molecular reorientation dynamics, a perylene bisimide-calixarene compound (1) shows additional on-off fluctuations due to its ability to undergo intramolecular excited state electron transfer (PET). This quenching process is turned on rather sharply when a film of poly(vinylacetate) containing 1 is heated above its glass transition temperature (T
g), which indicates that the electron transfer process depends on the availability of sufficient free volume. Spatial heterogeneities cause different individual molecules to reach the electron transfer regime at different temperatures, but these heterogeneities also fluctuate in time: in the matrix above T
g molecules that are mostly nonfluorescent due to PET can become fluorescent again on timescales of seconds to minutes.The two different mechanisms for intensity fluctuation, rotation and PET, thus far only observed in compound 1, make it a unique probe for the dynamics of supercooled liquids.
Publisher

Journal
Year
Volume
12
Issue
9
Pages
937-952
Physical description
Dates
published
1 - 9 - 2014
online
1 - 5 - 2014
Contributors
  • University of Amsterdam
  • Würzburg University
  • Würzburg University
  • University of Amsterdam
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YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-014-0544-0
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