Supramolecular complexes of podand ligands with xenon

• Authors: Błażej Gierczyk , Radosław Pankiewicz
• Languages of publication: EN

Abstracts

EN

Formation of stable complexes between xenon and podand polyoxyethylene ligands was ascertained. The complexation process was studied by 129Xe NMR titration, NMR diffusiometry and heteronuclear NOE measurements. The ligands studied form a 1:1 complexes with Xe(0). Their stability constants depend on the ligand structure, i.e., polyoxyethylene chain length, number of complexating polyether units and the topology of the anchoring centre.

Keywords

EN

Podand; Xenon; 129Xe NMR; Complexation; Supramolecular Chemistry

• Journal: Open Chemistry
• Year: 2014
• Volume: 12
• Issue: 5
• Pages: 624-634

Dates

published

1 - 5 - 2014

online

21 - 2 - 2014

Contributors

author

Błażej Gierczyk

• Adam Mickiewicz University in Poznań,

author

Radosław Pankiewicz

• Adam Mickiewicz University in Poznań

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Identifiers

DOI

10.2478/s11532-014-0525-3