Unusual potassium-oxalate coordination in the two-dimensional trimetallic [CoCl(NH3)5][KCr(C2O4)3]·0.5H2O complex

• Authors: Grzegorz Wrzeszcz , Andrzej Wojtczak , Magdalena Zawadzka
• Languages of publication: EN

Abstracts

EN

A new heterometallic compound, [CoCl(NH3)5][KCr(C2O4)3]·0.5H2O (1), has been synthesized and characterized by elemental analysis, IR and electronic spectra, thermal analysis, variable temperature magnetic susceptibility measurements, and single crystal X-ray diffraction. Compound 1 consists of two-dimensional [{KCr(C2O4)3}n]2n− layers, [CoCl(NH3)5]2+ ions and water molecules. Within the 2-D layer, three different types of oxalate coordination modes are present. Each K cation is coordinated by eight oxygen atoms from oxalate groups and also weakly interacts with the ninth oxygen atom. The extensive network of hydrogen bond is formed between the [KCr(C2O4)3]2− layer and the [CoCl(NH3)5]2+ ions. These interactions involve all hydrogen atoms of ammonia ligads and water molecule.

Keywords

EN

Crystal structure; Oxalate bridge; Coordination mode; Spectroscopy; Hydrogen bonding

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2014
• Volume: 12
• Issue: 6
• Pages: 652-658

Dates

published

1 - 6 - 2014

online

13 - 3 - 2014

Contributors

author

Grzegorz Wrzeszcz

• Nicolaus Copernicus University

author

Andrzej Wojtczak

• Nicolaus Copernicus University

author

Magdalena Zawadzka

• Nicolaus Copernicus University

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Identifiers

DOI

10.2478/s11532-014-0517-3