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Journal
2014 | 12 | 9 | 893-900
Article title

New high-pressures vapor-liquid equilibrium data for the carbon dioxide + 2-methyl-2-propanol binary system

Content
Title variants
Languages of publication
EN
Abstracts
EN
New vapor-liquid equilibria (VLE) data at 323.15, 333.15, 343.15, and 353.15 K and pressures up to 112.9 bar are reported for the carbon dioxide + 2-methyl-2-propanol system. The experimental method used in this work was a static analytical method with liquid and vapor phases sampling using a rapid online sampler injector (ROLSI™) coupled to a gas chromatograph (GC) for analysis. Measured VLE data and literature data for carbon dioxide + 2-methyl-2-propanol system were modeled with the Soave-Redlich-Kwong (SRK) cubic equation of state with classical van der Waals (two-parameter conventional mixing rule, 2PCMR) mixing rules. A single set of interaction parameters that lead to a correct phase behavior was used in this work to model the new VLE data and critical points of the mixtures in a wide range of temperature and pressure. The SRK prediction results were compared to the new data measured in this study and to available literature data.
Publisher

Journal
Year
Volume
12
Issue
9
Pages
893-900
Physical description
Dates
published
1 - 9 - 2014
online
1 - 5 - 2014
Contributors
author
  • University Politehnica of Bucharest, S1
author
author
  • University Politehnica of Bucharest, S1
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-013-0392-3
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