Application of NRTL activity coefficient model to describe the kinetics of gas adsorption

• Authors: Krzysztof Nieszporek , Tomasz Banach , Przemywslaw Podkościelny
• Languages of publication: EN

Abstracts

EN

The Non-Random Two-Liquid activity coefficient model is applied to describe the kinetics of pure gas adsorption on energetically heterogeneous solid surfaces. The surface energetic heterogeneity has been represented by the Gaussian-like function of the adsorption energy distribution. Two different kinetic isotherms have been presented. One of them, determined by using the statistical rate theory, has been critically discussed. The applicability of the presented approach has been demonstrated by a quantitative analysis of two sets of experimental data previously reported in the literature.

Keywords

EN

Thermodynamics; Kinetics; NRTL; Alkanes; Adsorption

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2014
• Volume: 12
• Issue: 2
• Pages: 185-193

Dates

published

1 - 2 - 2014

online

27 - 11 - 2013

Contributors

author

Krzysztof Nieszporek

• Maria Curie-Sklodowska University

author

Tomasz Banach

• Maria Curie-Sklodowska University

author

Przemywslaw Podkościelny

• Maria Curie-Sklodowska University

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Identifiers

DOI

10.2478/s11532-013-0367-4