Novel ion-binding C3 symmetric tripodal triazoles: synthesis and characterization

• Authors: Gábor Neumajer , Gergő Tóth , Szabolcs Béni , Béla Noszál
• Languages of publication: EN

Abstracts

EN

Novel C3 symmetric tripodal molecules were synthesized from cyclohexane 1,3,5-tricarboxylic acid. Utilizing click and Sonogashira reactions, ion-binding triazole and pyridazin-3(2H)-one units were incorporated to form polydentate ligands for ion complexation. The structures of the novel C3 symmetric derivatives were extensively characterized by 1H, 13C and 2D NMR techniques along with HRMS and IR. The copper(I)-binding potentials of these ligands were investigated by using them as additives in model copper(I)-catalysed azide-alkyne cycloaddition (CuAAC) reactions. The copper(I) complexation ability of our compound was also proved by different spectroscopic methods, such as mass spectrometry, UV and NMR spectroscopy. Based on the mass spectrometric data all of the C3 symmetric ligands formed 1:1 complex with copper(I) ion. The specific role of C3 symmetric polydentate form in the complexation process was also discussed [...]

Keywords

EN

Cycloaddition; NMR spectroscopy; CuAAC; RuAAC; Sonogashira reaction

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2014
• Volume: 12
• Issue: 1
• Pages: 115-125

Dates

published

1 - 1 - 2014

online

27 - 10 - 2013

Contributors

author

Gábor Neumajer

author

Gergő Tóth

author

Szabolcs Béni

author

Béla Noszál

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Identifiers

DOI

10.2478/s11532-013-0351-z