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2013 | 11 | 12 | 2005-2011
Article title

Corrosion depth profiles of nitrided titanium alloy in acidified sulphate solution

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EN
Abstracts
EN
Thick (400 µm) glow-discharge nitrided layers, TiN+Ti2N + αTi(N) type, have been produced on the Ti-1Al-1Mn titanium alloy. Using a progressive thinning method, the polarization characteristics at different depths of nitrided layers have been measured. From the plots of obtained potentiodynamic polarization curves the depth profiles of characteristic anodic and cathodic currents (at potentials corresponding to (a) hydride formation, (b) hydrogen evolution, (c) primary passivation, (d) oxygen evolution and (e) secondary passivation) as well as polarization resistance have been determined in 0.5 M Na2SO4 solution acidified to pH = 2. The anomalously high slope of the polarization curves in the cathodic region has been ascribed to the formation of titanium hydride. It has been shown that outer nitrided layers (up to 25 µm) exhibit excellent acid corrosion resistance owing to strong inhibition of the anodic process by TiN phase. Corrosion resistance of deeper situated layers gradually decreases and at depths of 250–370 µm the corrosion process is accelerated by presence of TiO2 precipitations. Nitrided layers, unlike the alloy core, allow oxygen evolution on the oxy-nitrided surface at potential of +1.6 V and at more positive potentials gradual transformation of the surfacial film into TiO2 takes place. Secondary passivation on nitrided titanium is less efficient than that in the absence of Ti-N species. [...]
Publisher

Journal
Year
Volume
11
Issue
12
Pages
2005-2011
Physical description
Dates
published
1 - 12 - 2013
online
26 - 9 - 2013
Contributors
  • Division of Chemistry, Faculty of Materials Engineering and Applied Physics, Czestochowa University of Technology, 42-200, Czestochowa, Poland, karina@wip.pcz.pl
author
  • Division of Chemistry, Faculty of Materials Engineering and Applied Physics, Czestochowa University of Technology, 42-200, Czestochowa, Poland
  • Faculty of Materials Science and Engineering, Warsaw University of Technology, PL-02 507, Warszawa, Poland
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-013-0342-0
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