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Journal
2013 | 11 | 9 | 1518-1526
Article title

The Ti-Fe-P system: phase equilibria and crystal structure of phases

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EN
Abstracts
EN
Abstract Phase equilibria was investigated in the Ti-Fe-P system at T = 1070 K in the region 0–67 at.% of P, employing X-ray powder diffraction. The two ternary compounds, namely Ti0.5–0.8Fe1.5−1.2P (Co2Si-type; space group Pnma; a = 0.5964(2)–0.6011(3), b = 0.3575(3)–0.3600(1), c = 0.6828(2)–0.6882(2) nm) and Ti0.85−1.25Fe1.15−0.75P (ZrNiAl-type; space group P-62m; a = 0.6071(4)–0.6117(1), c = 0.3510(9)–0.3506(1) nm) exist in the Ti-Fe-P system at this temperature. The crystal structure of the Ti0.85–1.25Fe1.15−0.75P compound was additionally determined by X-ray single crystal diffraction on the phase with stoichiometric composition. The substitutions of Ti by Fe were observed for Ti5P3.16, Ti3P and TiP phases, and Fe for Ti in the case of Fe3P, Fe2P binary compounds. Graphical abstract [...]
Publisher

Journal
Year
Volume
11
Issue
9
Pages
1518-1526
Physical description
Dates
published
1 - 9 - 2013
online
29 - 6 - 2013
Contributors
author
  • Laboratory MOLTECH — Anjou, UMR-CNRS 6200, University of Angers, 49045, Angers, France
  • Department of Analytical Chemistry, Ivan Franko National University of Lviv, UA-79005, Lviv, Ukraine, mashadzev@gmail.com
author
  • Department of Chemistry, University of Alberta, Edmonton, Alberta, T6G 2G2, Canada
  • Department of Analytical Chemistry, Ivan Franko National University of Lviv, UA-79005, Lviv, Ukraine
References
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-013-0282-8
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