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Journal

2013 | 11 | 9 | 1439-1446

Article title

In vitro bioactivity of Polyurethane/85S Bioglass composite scaffolds

Content

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EN

Abstracts

EN
In the present work Polyurethane (PU)/Bioglass (BG) composite materials were synthesized with different content of BG (10 and 20 mol.%) as filler. The 85S Bioglass was synthesized via polystep sol-gel method. The chemical composition of BG is 85SiO2-10CaO-5P2O5 (wt.%). The synthesis of PU was carried out by a two-step polyaddition reaction. The 85S BG was added in situ during the polymerization reaction. In vitro bioactivity of the prepared composites was examined in the presence of 1.5 SBF for 7 days in static conditions. The structure of synthesized PU/BG composites before and after in vitro test was determined by XRD, FTIR and SEM. XRD of the samples before in vitro test proved that the phase of γCa2P2O7 in the PU/20BG is visible. FTIR revealed the presence of urethane bond between OH-(from BG) and NCO groups (from PU). Based on FTIR results after in vitro test in 1.5 SBF solutions, A/B-carbonate containing hydroxyapatite (CO3HA) was formed. XRD proved that HA was formed on the surface of the samples, but Ca2P2O7 does not undergo any changes in the 1.5 SBF solution. SEM depicted the nano-HA agglomerated in spherical particles after immersion in 1.5 SBF for 7 days.

Publisher

Journal

Year

Volume

11

Issue

9

Pages

1439-1446

Physical description

Dates

published
1 - 9 - 2013
online
29 - 6 - 2013

Contributors

  • Department of Fundamental Chemical Technology, University of Chemical Technology and Metallurgy, Sofia, 1756, Bulgaria
  • Textile and Leather Department, University of Chemical Technology and Metallurgy, Sofia, 1756, Bulgaria
  • Department of Silicate Technology, University of Chemical Technology and Metallurgy, Sofia, 1756, Bulgaria

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-013-0273-9
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