Cobalt electrodeposition onto polycrystalline gold from ammoniacal solutions

• Authors: Luis Mendoza-Huizar , Clara Rios-Reyes
• Languages of publication: EN

Abstracts

EN

In the present work, the cobalt electrodeposition onto polycrystalline gold electrodes from aqueous solutions containing 0.01M CoSO4 + 1 M (NH4)2SO4 at pH=7 was analyzed. Linear voltammetry results suggested a change in the kinetic of the cobalt electrodeposition. In all cases, the nucleation rate (A), the number of active nucleation sites (N 0) and the saturation number of nuclei (N s ) values were potential dependent. The calculated Gibbs free energy (ΔG) for this system was 1.88×10−20 J nuclei−1 and the transfer coefficient for the Hydrogen Electroreduction Reaction (HER) was 0.47. [...]

Keywords

EN

Cobalt; Gold; Electrodeposition; Sulfate; Kinetic

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2013
• Volume: 11
• Issue: 8
• Pages: 1381-1392

Dates

published

1 - 8 - 2013

online

1 - 6 - 2013

Contributors

author

Luis Mendoza-Huizar

• Academic Area of Chemistry, Autonomous University of Hidalgo State, CP. 42186 Mineral de la Reforma, Hidalgo, Mexico

author

Clara Rios-Reyes

• Academic Academic Area of Earth Sciences and Materials, Autonomous University of Hidalgo State, CP. 42186 Mineral de la Reforma, Hidalgo, Mexico

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Identifiers

DOI

10.2478/s11532-013-0269-5