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Number of results

Journal

2013 | 11 | 7 | 1225-1238

Article title

Silylated gallium and indium chalcogenide ring systems as potential precursors to ME (E=O, S) materials

Content

Title variants

Languages of publication

EN

Abstracts

EN
The reaction of R3M (M=Ga, In) with HESiR′3 (E=O, S; R′3=Ph3, iPr3, Et3, tBuMe2) leads to the formation of (Me2GaOSiPh3)2(1); (Me2GaOSitBuMe2)2(2); (Me2GaOSiEt3)2(3); (Me2InOSiPh3)2(4); (Me2InOSitBuMe2)2(5); (Me2InOSiEt3)2(6); (Me2GaSSiPh3)2(7); (Et2GaSSiPh3)2(8); (Me2GaSSiiPr3)2(9); (Et2GaSSiiPr3)2(10); (Me2InSSiPh3)3(11); (Me2InSSiiPr3)n(12), in high yields at room temperature. The compounds have been characterized by multinuclear NMR and in most cases by X-ray crystallography. The molecular structures of (1), (4), (7) and (8) have been determined. Compounds (3), (6) and (10) are liquids at room temperature. In the solid state, (1), (4), (7) and (9) are dimers with central core of the dimer being composed of a M2E2 four-membered ring. VT-NMR studies of (7) show facile redistribution between four- and six-membered rings in solution. The thermal decomposition of (1)–(12) was examined by TGA and range from 200 to 350°C. Bulk pyrolysis of (1) and (2) led to the formation of Ga2O3; (4) and (5) In metal; (7)–(10) GaS and (11)–(12) InS powders, respectively. [...]

Publisher

Journal

Year

Volume

11

Issue

7

Pages

1225-1238

Physical description

Dates

published
1 - 7 - 2013
online
26 - 4 - 2013

Contributors

  • Department of Chemistry, Tulane University, 6823 Saint Charles Avenue, New Orleans, LA, 70118, USA
author
  • Department of Chemistry, Tulane University, 6823 Saint Charles Avenue, New Orleans, LA, 70118, USA
author
  • Department of Chemistry, Tulane University, 6823 Saint Charles Avenue, New Orleans, LA, 70118, USA
author
  • Department of Chemistry, Tulane University, 6823 Saint Charles Avenue, New Orleans, LA, 70118, USA

References

  • [1] M. Afzaal, P. O’Brien, J. Mat. Chem. 16, 1597 (2006) http://dx.doi.org/10.1039/b512182e[Crossref]
  • [2] J. Vittal, M. Ng, Acc. Chem. Res. 39, 869 (2006) http://dx.doi.org/10.1021/ar050224s[Crossref]
  • [3] A. Jones, P. O’Brien, CVD of Compound Semiconductors: Precursor Synthesis and Development (VCH, New York, 1997) http://dx.doi.org/10.1002/9783527614639[Crossref]
  • [4] J. Oliver, J. Organomet. Chem. 500 (1995)
  • [5] S. Suh, D. Hoffman, J. Am. Chem. Soc. 122, 939 (2000) http://dx.doi.org/10.1021/ja000845a[Crossref]
  • [6] J. Park, G. Horley, P. ’Brien, A. Jones, M. Motevalli, J. Mat. Chem. 11, 2346 (2001) http://dx.doi.org/10.1039/b102212l[Crossref]
  • [7] A. MacInnes, M. Power, A. Barron, Chem. Mater. 5, 1344 (1993) http://dx.doi.org/10.1021/cm00033a027[Crossref]
  • [8] S. Schulz, E. Gillan, J. Ross, L. Rogers, R. Rogers, A. Barron, Organometallics 15, 4880 (1996) http://dx.doi.org/10.1021/om960480w[Crossref]
  • [9] A. MacInnes, M. Power, A. Barron, Chem. Mater. 4, 11 (1992) http://dx.doi.org/10.1021/cm00019a005[Crossref]
  • [10] M. Lazell, P. O’Brien, D. Otway, J. Park, Chem. Mater. 11, 3430 (1999) http://dx.doi.org/10.1021/cm9905040[Crossref]
  • [11] G. Shang, M. Hampden-Smith, E. Duesler, Chem. Commun. 1996, 1733 (1996) http://dx.doi.org/10.1039/cc9960001733[Crossref]
  • [12] P. O’Brien, D. Otway, J. Walsh, J. Chem. Vapor Depos. 3, 227 (1997) http://dx.doi.org/10.1002/cvde.19970030411[Crossref]
  • [13] A. Keys, S. Bott, A. Barron, Chem. Mater. 11, 3578 (1999) http://dx.doi.org/10.1021/cm9903632[Crossref]
  • [14] D. Fan, M. Afzaal, M. Mallik, C. Nguyen, P. O’Brien, P. Thomas, Coord. Chem. Rev. 251, 1878 (2007) http://dx.doi.org/10.1016/j.ccr.2007.03.021[Crossref]
  • [15] N. Vyazankin, M. Bochkarev, A. Charov J. Organomet. Chem. 27, 175 (1971) http://dx.doi.org/10.1016/S0022-328X(00)80562-8[Crossref]
  • [16] J. Janik, R. Wells, V. Young Jr., A. Rheingold, I. Guzei, J. Am. Chem. Soc. 120, 532 (1998) http://dx.doi.org/10.1021/ja9731837[Crossref]
  • [17] E. Foos, R. Jouet, R. Wells, A. Rheingold, L. Liable-Sands, J. Organomet. Chem. 582, 45 (1999) http://dx.doi.org/10.1016/S0022-328X(98)01184-X[Crossref]
  • [18] R. Jouet, R. Wells, A. Rheingold, C. Incarvito, J. Organomet. Chem. 601, 191 (2000) http://dx.doi.org/10.1016/S0022-328X(00)00055-3[Crossref]
  • [19] C. Carmalt, J. Mileham, A. White, D. Williams, J. Steeds, Inorg. Chem. 40, 6035 (2001) http://dx.doi.org/10.1021/ic010507q[Crossref]
  • [20] S. Weinrich, H. Piotrowski,, M. Vogt, A. Schulz, M. Westerhausen, Inorg. Chem. 43, 3756 (2004) http://dx.doi.org/10.1021/ic0303284[Crossref]
  • [21] D. Tran, J. Corrigan, Organometallics 19, 5202 (2000) http://dx.doi.org/10.1021/om000624d[Crossref]
  • [22] J. Corrigan, Chem. Commun. 1997, 1837 (1997) http://dx.doi.org/10.1039/a704132b[Crossref]
  • [23] M. DeGroot, N. Taylor, J. Corrigan, J. Am. Chem. Soc. 125, 864 (2003) http://dx.doi.org/10.1021/ja028800s[Crossref]
  • [24] A. Wallbank, A. Borecki, N. Taylor, J. Corrigan, Organometallics 24, 788 (2005) http://dx.doi.org/10.1021/om049238c[Crossref]
  • [25] E. Turner, H. Rösner, D. Fenske, Y. Huang, J. Corrigan, J. Phys. Chem. B 110, 16261 (2006) http://dx.doi.org/10.1021/jp060135c[Crossref]
  • [26] E. Turner, H. Rösner, Y. Huang, J. Corrigan, J. Phys. Chem. C 111, 7319 (2007) http://dx.doi.org/10.1021/jp067833h[Crossref]
  • [27] P. Bonasia, V. Christou, J. Arnold, J. Am. Chem. Soc. 115, 6777 (1993) http://dx.doi.org/10.1021/ja00068a039[Crossref]
  • [28] D. Shriver, M. Drezdon, The manipulation of air-sensitive compounds, 2nd edition (Wiley-Interscience, New York, 1986)
  • [29] Bruker (2000)- SMART, Version 5.625. (Bruker AXS Inc., Madison, Wisconsin, USA)
  • [30] Bruker (2004), SAINT Plus, Version 6.35A (Bruker AXS Inc., Madison, Wisconsin, USA)
  • [31] G.M. Sheldrick, SADABS, Version 2.05 (University of Göttingen, Germany, 2002)
  • [32] Bruker (2000), SHELXTL, Version 6.10. (Bruker AXS Inc., Madison, Wisconsin, USA)
  • [33] G.M. Sheldrick, SHELXS97 and SHELXL97 (University of Göttingen, Germany, 1997)
  • [34] M. Valet, D. Hoffman, Chem. Mater. 13, 2135 (2001) http://dx.doi.org/10.1021/cm0014177[Crossref]
  • [35] D. Bradley, D. Frigo, M. Hursthouse, B. Hussain, Organometallics 7, 1112 (1988) http://dx.doi.org/10.1021/om00095a015[Crossref]
  • [36] G. Linti, W. Köstler, Angew. Chemie Internat. Edit. Engl. 35, 550 (1996) http://dx.doi.org/10.1002/anie.199605501[Crossref]
  • [37] Z. Zhu, R. Wright, Z. Brown, A. Fox, A. Phillips, A. Richards, M. Olmstead, P. Powe, Organometallics 28, 2512 (2009) http://dx.doi.org/10.1021/om900031v[Crossref]
  • [38] H. Schumann, J. Kaufmann, B. Wassermann, F. Girgsdies, N. Jaber, J. Blum, Z. Anorgan. Allgem. Chemie 628, 971 (2002) http://dx.doi.org/10.1002/1521-3749(200206)628:5<971::AID-ZAAC971>3.0.CO;2-G[Crossref]
  • [39] M. Self, A. McPhail, R. Wells, J. Coord. Chem. 29, 27 (1993) http://dx.doi.org/10.1080/00958979308037122[Crossref]
  • [40] S. Chitsaz, B. Neumüller, Z. Anorgan. Allgem. Chemie 627, 2451 (2001) http://dx.doi.org/10.1002/1521-3749(200111)627:11<2451::AID-ZAAC2451>3.0.CO;2-H[Crossref]
  • [41] O. Beachley Jr., D. Rosenblum, M. Churchill, C. Lake, L. Toomey, Organometallics 15, 3653 (1996) http://dx.doi.org/10.1021/om960284p[Crossref]
  • [42] I. E. Medina, Master’s thesis, Department of Chemistry (Tulane University, Tulane, 2002)
  • [43] H. Rahbarnoohi, M. Taghiof, M. Heeg, D. Dick, J. Oliver, Inorg. Chem. 33, 6307 (1994) http://dx.doi.org/10.1021/ic00104a047[Crossref]
  • [44] M. Taghiof, M. Heeg, M. Bailey, D. Dick, R. Kumar, D. Hendershot, H. Rahbarnoohi, J. Oliver, Organometallics 14, 2903 (1995) http://dx.doi.org/10.1021/om00006a040[Crossref]
  • [45] D. Hendershot, R. Kumar, M. Barber, J. Oliver, Organometallics 10, 1917 (1991) http://dx.doi.org/10.1021/om00052a043[Crossref]
  • [46] G. Hoffmann, C. Burschka, Angew. Chemie Internat. Edit. Engl. 24, 970 (1985) http://dx.doi.org/10.1002/anie.198509701[Crossref]
  • [47] M. Power, A. Barron, Chem. Commun. 1991, 1315 (1991) [Crossref]
  • [48] G. Hoffmann, C. Burschka, J. Organomet. Chem. 267, 229 (1984) http://dx.doi.org/10.1016/0022-328X(84)80193-X[Crossref]
  • [49] S. Ghazi, M. Heeg, J. Oliver, Inorg. Chem. 33, 4517 (1994) http://dx.doi.org/10.1021/ic00098a018[Crossref]
  • [50] I. Medina, M. Fink, Mater. Science Eng. B 116, 375 (2005) http://dx.doi.org/10.1016/j.mseb.2004.05.051[Crossref]

Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-013-0255-y
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