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Journal
2013 | 11 | 7 | 1172-1186
Article title

Carbon nanotube-ionic liquid nanocomposite modified carbon-ceramic electrode for determination of dopamine in real samples

Content
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Languages of publication
EN
Abstracts
EN
Room temperature 1-butyl-3-methylimidazolium tetraflouroborate ([BMIM][BF4]) ionic liquid was employed for dispersion of multi walled carbon nanotubes (MWCNTs) and the formation of nanocomposite on the surface of a carbon-ceramic electrode. The surface of the modified electrode was characterized using scanning electron microscopy and electrochemical impedance spectroscopy. The modified electrode exhibited excellent electrochemical activity to oxidation of dopamine (DA); whereas electro oxidation of ascorbic acid (AA) was not seen and electro oxidation of uric acid (UA) appeared at a more positive potential than DA. The multi walled carbon nanotube-ionic liquid nanocomposite modified carbon-ceramic electrode was used for the selective determination of DA in the presence of high levels of AA and UA using differential pulse voltammetry. The calibration curve for DA was linear in the range of 3.00 to 130 µM with the detection limit (S/N=3) of 0.87 µM. The present electrode was successfully applied to the determination of DA in some commercial pharmaceutical samples and human blood serum. [...]
Publisher

Journal
Year
Volume
11
Issue
7
Pages
1172-1186
Physical description
Dates
published
1 - 7 - 2013
online
26 - 4 - 2013
Contributors
author
  • Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, 51664, Iran, sr.majidi@gmail.com
author
  • Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, 51664, Iran
  • Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, 51664, Iran
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-013-0251-2
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