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Number of results

Journal

2013 | 11 | 7 | 1132-1136

Article title

Oxygen sensing materials based on clay/metalloporphyrin hybrid systems

Content

Title variants

Languages of publication

EN

Abstracts

EN
This study was focused on the investigation of novel hybrid organo/inorganic systems for oxygen sensing applications. As a host material, a synthetic clay mineral Sumecton SA was chosen, while, as guest materials, metalloporphyrins containing Pt(II) and Pd(II) were chosen. These are known to be very efficient agents for sensing applications because of a “heavy atom effect”. This effect promotes a spin-orbit coupling, resulting in the fact that almost all of the radiation from a singlet excited state undergoes intersystem crossing, followed by a de-excitation via a triplet state. The combination of metalloporphyrin and layered materials enables unique oxygen sensing properties due to the steric effects of layered materials. The result is that the emission from the membrane was sensitive at the range around aerobic conditions. The spectroscopic analysis of hybrid systems - clay/porphyrin membranes (CPMs) showed that these materials can serve as prospective candidates for the construction of effective, reliable and economical oxygen sensors. [...]

Publisher

Journal

Year

Volume

11

Issue

7

Pages

1132-1136

Physical description

Dates

published
1 - 7 - 2013
online
26 - 4 - 2013

Contributors

  • Institute of Inorganic Chemistry, Slovak Academy of Sciences, 845 36, Bratislava, Slovakia
  • Institute of Inorganic Chemistry, Slovak Academy of Sciences, 845 36, Bratislava, Slovakia

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-013-0238-z
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