Oxygen sensing materials based on clay/metalloporphyrin hybrid systems

• Authors: Alexander Čeklovský , Shinsuke Takagi
• Languages of publication: EN

Abstracts

EN

This study was focused on the investigation of novel hybrid organo/inorganic systems for oxygen sensing applications. As a host material, a synthetic clay mineral Sumecton SA was chosen, while, as guest materials, metalloporphyrins containing Pt(II) and Pd(II) were chosen. These are known to be very efficient agents for sensing applications because of a “heavy atom effect”. This effect promotes a spin-orbit coupling, resulting in the fact that almost all of the radiation from a singlet excited state undergoes intersystem crossing, followed by a de-excitation via a triplet state. The combination of metalloporphyrin and layered materials enables unique oxygen sensing properties due to the steric effects of layered materials. The result is that the emission from the membrane was sensitive at the range around aerobic conditions. The spectroscopic analysis of hybrid systems - clay/porphyrin membranes (CPMs) showed that these materials can serve as prospective candidates for the construction of effective, reliable and economical oxygen sensors. [...]

Keywords

EN

Porphyrin; Clay; Oxygen sensor; Visible spectroscopy; Phosphorescence

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2013
• Volume: 11
• Issue: 7
• Pages: 1132-1136

Dates

published

1 - 7 - 2013

online

26 - 4 - 2013

Contributors

author

Alexander Čeklovský

• Institute of Inorganic Chemistry, Slovak Academy of Sciences, 845 36, Bratislava, Slovakia

author

Shinsuke Takagi

• Institute of Inorganic Chemistry, Slovak Academy of Sciences, 845 36, Bratislava, Slovakia

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Identifiers

DOI

10.2478/s11532-013-0238-z