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Number of results

Journal

2013 | 11 | 6 | 1001-1009

Article title

Synthesis and characterization of 2CuCN·DMSO and [CuII(DMSO)6][CuI
6(CN)8] 3-D framework compounds

Content

Title variants

Languages of publication

EN

Abstracts

EN
Two novel complexes of CuCN were characterized by using a single-crystal X-ray diffraction technique and Raman spectroscopy. In the structure of 2CuCN·DMSO ligand molecule demonstrates unique bridging mode, being bound to two CuI centers via oxygen and sulfur atoms. The bridging role of both CN groups and DMSO molecules results in the formation of (CuCN·DMSO)n framework. Along the channels of the network are running infinite zig-zag (CuCN)n chains, which are bound to the framework by elongated Cu…(CN) bonds. A mixed-valence [CuII(DMSO)6][CuI
6(CN)8] compound is composed of 3-D [CuI
6(CN)8]n anionic framework and located in the channels of partially disordered [CuII(DMSO)6]2+ cations.

Publisher

Journal

Year

Volume

11

Issue

6

Pages

1001-1009

Physical description

Dates

published
1 - 6 - 2013
online
28 - 3 - 2013

Contributors

  • Department of Inorganic Chemistry and Technology, Institute Jožef Stefan, 1000, Ljubljana, Slovenia
  • Department of Inorganic Chemistry and Technology, Institute Jožef Stefan, 1000, Ljubljana, Slovenia

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-013-0232-5
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