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Journal
2013 | 11 | 6 | 1001-1009
Article title

Synthesis and characterization of 2CuCN·DMSO and [CuII(DMSO)6][CuI
6(CN)8] 3-D framework compounds

Content
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EN
Abstracts
EN
Two novel complexes of CuCN were characterized by using a single-crystal X-ray diffraction technique and Raman spectroscopy. In the structure of 2CuCN·DMSO ligand molecule demonstrates unique bridging mode, being bound to two CuI centers via oxygen and sulfur atoms. The bridging role of both CN groups and DMSO molecules results in the formation of (CuCN·DMSO)n framework. Along the channels of the network are running infinite zig-zag (CuCN)n chains, which are bound to the framework by elongated Cu…(CN) bonds. A mixed-valence [CuII(DMSO)6][CuI
6(CN)8] compound is composed of 3-D [CuI
6(CN)8]n anionic framework and located in the channels of partially disordered [CuII(DMSO)6]2+ cations.
Publisher

Journal
Year
Volume
11
Issue
6
Pages
1001-1009
Physical description
Dates
published
1 - 6 - 2013
online
28 - 3 - 2013
Contributors
  • Department of Inorganic Chemistry and Technology, Institute Jožef Stefan, 1000, Ljubljana, Slovenia, andrii.vakulka@ijs.si
  • Department of Inorganic Chemistry and Technology, Institute Jožef Stefan, 1000, Ljubljana, Slovenia
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-013-0232-5
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