Synthesis and characterization of 2CuCN·DMSO and [CuII(DMSO)6][CuI
6(CN)8] 3-D framework compounds

• Authors: Andrii Vakulka , Evgeny Goreshnik
• Languages of publication: EN

Abstracts

EN

Two novel complexes of CuCN were characterized by using a single-crystal X-ray diffraction technique and Raman spectroscopy. In the structure of 2CuCN·DMSO ligand molecule demonstrates unique bridging mode, being bound to two CuI centers via oxygen and sulfur atoms. The bridging role of both CN groups and DMSO molecules results in the formation of (CuCN·DMSO)n framework. Along the channels of the network are running infinite zig-zag (CuCN)n chains, which are bound to the framework by elongated Cu…(CN) bonds. A mixed-valence [CuII(DMSO)6][CuI
6(CN)8] compound is composed of 3-D [CuI
6(CN)8]n anionic framework and located in the channels of partially disordered [CuII(DMSO)6]2+ cations.

Keywords

EN

Copper(I) cyanide; Dimethylsulfoxide; σ-complex; Infinite chains; 3-D framework

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2013
• Volume: 11
• Issue: 6
• Pages: 1001-1009

Dates

published

1 - 6 - 2013

online

28 - 3 - 2013

Contributors

author

Andrii Vakulka

• Department of Inorganic Chemistry and Technology, Institute Jožef Stefan, 1000, Ljubljana, Slovenia

author

Evgeny Goreshnik

• Department of Inorganic Chemistry and Technology, Institute Jožef Stefan, 1000, Ljubljana, Slovenia

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Identifiers

DOI

10.2478/s11532-013-0232-5