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Journal
2013 | 11 | 6 | 912-919
Article title

Comparative studies of Pd, Ru, Ni, Cu/ZnAl2O4 catalysts for the water gas shift reaction

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EN
Abstracts
EN
The activity of monometallic Pd, Ru, Ni and Cu catalysts supported on spinel ZnAl2O4 for water gas shift reaction (WGS) was investigated. The physicochemical properties of each catalyst was studied by XRD, TPR, BET and chemisorption methods. The highest activity was obtained for Cu/ZnAl2O4 among the catalysts tested. The activation process carried out in a reducing atmosphere 5%H2-95%Ar in the case of Cu/ZnAl2O4 system lead to the catalytic activity improvement. In the case of copper catalysts, the water gas shift reaction proceeded by the redox surface mechanism between Cu0/Cu+. The PdZn alloy formation after reduction at 350°C was shown. [...]
Publisher

Journal
Year
Volume
11
Issue
6
Pages
912-919
Physical description
Dates
published
1 - 6 - 2013
online
28 - 3 - 2013
Contributors
  • Institute of General and Ecological Chemistry, Lodz University of Technology, 90-924, Łódź, Poland, mierczyn25@wp.pl
  • Institute of General and Ecological Chemistry, Lodz University of Technology, 90-924, Łódź, Poland
  • Institute of General and Ecological Chemistry, Lodz University of Technology, 90-924, Łódź, Poland
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-013-0223-6
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