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Number of results

Journal

2013 | 11 | 4 | 561-568

Article title

Rhodium catalysts build into the structure of a silicate support in the hydroformylation of alkenes

Content

Title variants

Languages of publication

EN

Abstracts

EN
Rhodium is build into a nano-structured calcium silicate during the synthesis of the silicate. Thereby, it was desired to create a robust heterogeneous catalyst, which does not suffer from catalyst leaching like rhodium impregnated on a pre-formed silicate. While this was achieved, the silicate structure was adversely affected by the incorporation of rhodium - the surface area and pore volume of the material were found to be comparatively low. Alcohol and acid washing were tested to address this issue. The alcohol treatment proved detrimental as catalytic material was leached from the silicate. The acid washed rhodium containing calcium silicate was quite active in the hydroformylation of alkenes and did not suffer loss of catalyst into the product phase. Acid treated rhodium containing silicates were more active than their untreated counterparts but less selective due to access to the rhodium centers being opened. [...]

Publisher

Journal

Year

Volume

11

Issue

4

Pages

561-568

Physical description

Dates

published
1 - 4 - 2013
online
23 - 1 - 2013

Contributors

  • School of Chemical and Physical Sciences, Victoria University of Wellington, P. O. Box 600, 6140, Wellington, New Zealand
  • School of Chemical and Physical Sciences, Victoria University of Wellington, P. O. Box 600, 6140, Wellington, New Zealand
author
  • Inorganic Chemistry Department, Georg-August-University Göttingen, 37077, Göttingen, Germany
  • School of Chemical and Physical Sciences, Victoria University of Wellington, P. O. Box 600, 6140, Wellington, New Zealand

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_s11532-012-0186-z
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