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Journal
2013 | 11 | 4 | 561-568
Article title

Rhodium catalysts build into the structure of a silicate support in the hydroformylation of alkenes

Content
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Languages of publication
EN
Abstracts
EN
Rhodium is build into a nano-structured calcium silicate during the synthesis of the silicate. Thereby, it was desired to create a robust heterogeneous catalyst, which does not suffer from catalyst leaching like rhodium impregnated on a pre-formed silicate. While this was achieved, the silicate structure was adversely affected by the incorporation of rhodium - the surface area and pore volume of the material were found to be comparatively low. Alcohol and acid washing were tested to address this issue. The alcohol treatment proved detrimental as catalytic material was leached from the silicate. The acid washed rhodium containing calcium silicate was quite active in the hydroformylation of alkenes and did not suffer loss of catalyst into the product phase. Acid treated rhodium containing silicates were more active than their untreated counterparts but less selective due to access to the rhodium centers being opened. [...]
Publisher

Journal
Year
Volume
11
Issue
4
Pages
561-568
Physical description
Dates
published
1 - 4 - 2013
online
23 - 1 - 2013
Contributors
  • School of Chemical and Physical Sciences, Victoria University of Wellington, P. O. Box 600, 6140, Wellington, New Zealand, aoc@gmx.li
  • School of Chemical and Physical Sciences, Victoria University of Wellington, P. O. Box 600, 6140, Wellington, New Zealand
author
  • Inorganic Chemistry Department, Georg-August-University Göttingen, 37077, Göttingen, Germany
  • School of Chemical and Physical Sciences, Victoria University of Wellington, P. O. Box 600, 6140, Wellington, New Zealand
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-012-0186-z
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