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2013 | 11 | 4 | 471-484
Article title

Applicability of Gd-doped BaZrO3, SrZrO3, BaCeO3 and SrCeO3 proton conducting perovskites as electrolytes for solid oxide fuel cells

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EN
Abstracts
EN
Four proton conducting oxides of perovskite structure: BaZrO3, SrZrO3, BaCeO3 and SrCeO3 doped with 5 mol.% of gadolinium are compared in terms of crystal structure, microstructure, sinterability, water sorption ability, ionic transference number, electrical conductivity and stability towards CO2. Relations between proton conductivity, structural and chemical parameters: pseudo-cubic unit cell volume, lattice free volume, tolerance factor, crystal symmetry and electronegativity are discussed. The grain boundary resistance is shown to be the limiting factor of total proton-conductivity for the materials examined. The highest proton conductivity was observed for BaCeO3, however, it turned out to be prone to degradation in CO2-containing atmosphere and reduction at high temperatures. On the other hand, Ba and Sr zirconates are found to be more chemically stable, but exhibit low electrical conductivity. Electrical conductivity relaxation upon hydration is used to calculate proton diffusion coefficient. Selected materials were tested as electrolytes in solid oxide fuel cells. [...]
Publisher

Journal
Year
Volume
11
Issue
4
Pages
471-484
Physical description
Dates
published
1 - 4 - 2013
online
23 - 1 - 2013
Contributors
  • Department of Hydrogen Energy, Faculty of Energy and Fuels, AGH University of Science and Technology, 30-059, Kraków, Poland, wojciech.zajac@agh.edu.pl
  • Department of Hydrogen Energy, Faculty of Energy and Fuels, AGH University of Science and Technology, 30-059, Kraków, Poland
author
  • Department of Hydrogen Energy, Faculty of Energy and Fuels, AGH University of Science and Technology, 30-059, Kraków, Poland
  • Department of Hydrogen Energy, Faculty of Energy and Fuels, AGH University of Science and Technology, 30-059, Kraków, Poland
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_s11532-012-0144-9
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