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2012 | 10 | 6 | 1709-1759
Article title

Crystallographic and structural characterization of heterometallic platinum compounds. Part II. Heterobinuclear Pt compounds with Pt⋯M (M = transition or lantanide metal) > 3.0 Å

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Abstracts
EN
This review covers almost two hundred and twenty heterobinuclear platinum compounds in which Pt⋯M separation is over 3.0 Å. The M is a transition metal (Cu, Ag, Au, Ti, V, Cr, Mo, W, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni and Pd). There is an example of a lanthanide, Yb and a actinide, U. The Pt atom has oxidation numbers 0, +2 and +4. The Pt coordination geometries include trigonal planar Pt(0); square planar Pt(II); trigonal bipyramidal, and pseudo octahedral Pt(IV), with the most frequent being square planar. The most common ligands for Pt are P and C donor atoms, as well as a chlorine atom. The Pt - Ag distance of 3.002(1) Å is the shortest found in this series. There are examples which contain two crystallographically independent molecules, which differ mostly by degree of distortion and even one unique example, which contains eight such molecules. These are examples of distortion isomerism. Factors affecting bond lengths and angles are discussed and some ambiguities in coordination polyhedral are outlined.
Publisher

Journal
Year
Volume
10
Issue
6
Pages
1709-1759
Physical description
Dates
published
1 - 12 - 2012
online
21 - 9 - 2012
Contributors
author
  • Department of Pharmacology and Toxicology, Faculty of Pharmacy, Comenius University, 832 32, Bratislava, Slovak Republic, qmelnik@stuba.sk
  • Department of Pharmacology and Toxicology, Faculty of Pharmacy, Comenius University, 832 32, Bratislava, Slovak Republic
  • Department of Chemistry, York University, North York, M3J 1P3, Ontario, Canada
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